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1.
《International Journal of Hydrogen Energy》2022,47(100):42280-42292
In this study, the separation of hydrogen from gas mixtures using a palladium membrane coupled with a vacuum environment on the permeate side was studied experimentally. The gas mixtures composed of H2, N2, and CO2 were used as the feed. Hydrogen permeation fluxes were measured with membrane operating temperature in the range of 320–380 °C, pressures on the retentate side in the range of 2–5 atm, and vacuum pressures on the permeate side in the range of 15–51 kPa. The Taguchi method was used to design the operating conditions for the experiments based on an orthogonal array. Using the measured H2 permeation fluxes from the Taguchi approach, the stepwise regression analysis was also employed for establishing the prediction models of H2 permeation flux, followed by the analysis of variance (ANOVA) to identify the significance and suitability of operating conditions. Based on both the Taguchi approach and ANOVA, the H2 permeation flux was mostly affected by the gas mixture composition, followed by the retentate side pressure, the vacuum degree, and the membrane temperature. The predicted optimal operating conditions were the gas mixture with 75% H2 and 25% N2, the membrane temperature of 320 °C, the retentate side pressure of 5 atm, and the vacuum degree of 51 kPa. Under these conditions, the H2 permeation flux was 0.185 mol s?1 m?2. A second-order normalized regression model with a relative error of less than 7% was obtained based on the measured H2 permeation flux. 相似文献
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3.
《International Journal of Hydrogen Energy》2022,47(24):12159-12178
This paper proposes a novel method combining Pinch Methodology and waste hydrogen recovery, aiming to minimise fresh hydrogen consumption and waste hydrogen discharge. The method of multiple-level resource Pinch Analysis is extended to the level of Total Site Hydrogen Integration by considering fresh hydrogen sources with various quality. Waste hydrogen after Total Site Integration is further regenerated. The technical feasibility and economy of the various purification approaches are considered, demonstrated with a case study of a refinery hydrogen network in a petrochemical industrial park. The results showed that fresh hydrogen usage and waste hydrogen discharge could be reduced by 21.3% and 67.6%. The hydrogen recovery ratio is 95.2%. It has significant economic benefits and a short payback period for Total Site Hydrogen Integration with waste hydrogen purification. The proposed method facilitates the reuse of waste hydrogen before the purification process that incurs an additional environmental footprint. In line with the Circular Economy principles, hydrogen resource is retained in the system as long as possible before discharge. 相似文献
4.
This paper presents the stability improvement results of hybrid doubly fed induction generator (DFIG)-based and permanent magnet generator (PMG)-based offshore wind farms (OWFs) using a static synchronous series compensator (SSSC). An adaptive-network-based fuzzy inference system (ANFIS) controller of the proposed SSSC is designed to render adequate damping characteristics to the studied system. A frequency-domain approach based on a linearized system model using eigenvalue technique analysis is performed. A time-domain scheme based on a nonlinear system model subject to a three-phase short circuit fault at infinite bus with variations in the signal transmission delays has also been investigated to compare the damping of the studied system in cases of with and without controller. The simulation results with MATLAB/SIMULINK toolbox have been presented. It can be concluded from the simulation results that the proposed SSSC joined with the designed ANFIS damping controller can offer adequate damping performance to the studied hybrid DFIG-based and PMG-based OWFs under severe disturbance. 相似文献
5.
针对工业控制系统传统单一检测算法模型对不同攻击类型检测率和检测速度不佳的问题,提出一种优化支持向量机和K-means++算法结合的入侵检测模型。首先利用主成分分析法(PCA)对原始数据集进行预处理,消除其相关性;其次在粒子群优化(PSO)算法的基础上加入自适应变异过程避免在训练的过程中陷入局部最优解;然后利用自适应变异粒子群优化(AMPSO)算法优化支持向量机的核函数和惩罚参数;最后利用密度中心法改进K-means算法与优化后的支持向量机组合成入侵检测模型,从而实现工业控制系统的异常检测。实验结果表明,所提方法在检测速度和对各类攻击的检测率上得到明显提升。 相似文献
6.
1-read/1-write (1R1W) register file (RF) is a popular memory configuration in modern feature rich SoCs requiring significant amount of embedded memory. A memory compiler is constructed using the 8T RF bitcell spanning a range of instances from 32 b to 72 Kb. An 8T low-leakage bitcell of 0.106 μm2 is used in a 14 nm FinFET technology with a 70 nm contacted gate pitch for high-density (HD) two-port (TP) RF memory compiler which achieves 5.66 Mb/mm2 array density for a 72 Kb array which is the highest reported density in 14 nm FinFET technology. The density improvement is achieved by using techniques such as leaf-cell optimization (eliminating transistors), better architectural planning, top level connectivity through leaf-cell abutment and minimizing the number of unique leaf-cells. These techniques are fully compatible with memory compiler usage over the required span. Leakage power is minimized by using power-switches without degrading the density mentioned above. Self-induced supply voltage collapse technique is applied for write and a four stack static keeper is used for read Vmin improvement. Fabricated test chips using 14 nm process have demonstrated 2.33 GHz performance at 1.1 V/25 °C operation. Overall Vmin of 550 mV is achieved with this design at 25 °C. The inbuilt power-switch improves leakage power by 12x in simulation. Approximately 8% die area of a leading 14 nm SoC in commercialization is occupied by these compiled RF instances. 相似文献
7.
根据Flether等人的研究,基于感知独立性假设的子带识别方法被用于抗噪声鲁棒语音识别。本文拓展子带方法,采用基于噪声污染假定的多带框架来减少噪声影响。论文不仅从理论上分析了噪声污染假定多带框架在识别性能上的潜在优势,而且提出了多带环境下的鲁棒语音识别算法。研究表明:多带框架不仅回避了独立感知假设要求,而且与子带方法相比,多带方法能更好的减少噪声影响,提高系统识别性能。 相似文献
8.
Aqueous solutions of poly(vinyl pyrrolidone)-fullerene complexes (PVP-C70) have been studied using static and dynamic light scattering methods. Two diffusive processes were detected. The slow diffusion was interpreted as dynamics of large intermolecular PVP-C70 complexes while the fast diffusion was associated with the presence of individual PVP molecules in solution. It was also shown that the molecular weights and dimensions of PVP-C70 complexes are smaller than for PVP-C60 by a factor of 2.5-3. In aqueous solutions of PVP-C70 complex the depolarization and dissymmetry of scattered light were observed in contrast to PVP-C60 solutions. It reveals the existence of anisotropic structures in PVP-C70 solutions. Intermolecular interactions within PVP-C70 complexes are weak and a hydrodynamic field can destroy complexes. 相似文献
9.
Field Static Load Test on Kao-Ping-Hsi Cable-Stayed Bridge 总被引:1,自引:0,他引:1
Field load testing is an effective method for understanding the behavior and fundamental characteristics of a cable-stayed bridge. This paper presents the results of field static load tests on the Kao-Ping-Hsi cable-stayed bridge, the longest cable-stayed bridge in Taiwan, before it was open to traffic. A total of 40 loading cases, including the unit and distributed bending and torsion loading effects, were conducted to investigate the bridge behavior. The atmospheric temperature effect on the variations of the main girder deflections was also monitored. The results of static load testing include the main girder deflections, the flexural strains of the prestressed concrete girder, and the variations of the cable forces. A three-dimensional finite-element model was developed. The results show that the bridge under the planned load test conditions has linear superposition characteristics and the analytical model shows a very good agreement with the bridge responses. Further discussion of deflection and cable forces of the design specifications for a cable-stayed bridge is also presented. 相似文献
10.
Flow-mode static and dynamic laser light scattering (SLS/DLS) studies of polymers, including polystyrene, polyethylene, polypropylene and poly(dimethylsiloxane) (PDMS), in 1,2,4-trichlorobenzene (TCB) at 150 °C were performed on a high temperature gel permeation chromatography (GPC) coupled with a SLS/DLS detector. Both absolute molecular weight (M) and molecular sizes (radius of gyration, Rg and hydrodynamic radius, Rh) of polymers eluting from the GPC columns were obtained simultaneously. The conformation of different polymers in TCB at 150 °C were discussed according to the scaling relationships between Rg, Rh and M and the ρ-ratio (ρ=Rg/Rh). Flow-mode DLS results of PDMS were verified by batch-mode DLS study of the same sample. The presented technique was proved to be a convenient and quick method to study the shape and conformation of polymers in solution at high temperature. However, the flow-mode DLS was only applicable for high molecular weight polymers with a higher refractive index increment such as PDMS. 相似文献