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1.
《International Journal of Hydrogen Energy》2022,47(87):36831-36842
Two electron oxygen reduction reaction to produce hydrogen peroxide (H2O2) is a promising alternative technique to the multistep and high energy consumption anthraquinone process. Herein, Ni–Fe layered double hydroxide (NiFe-LDH) has been firstly demonstrated as an efficient bifunctional catalyst to prepare H2O2 by electrochemical oxygen reduction (2e? ORR) and oxygen evolution reaction (OER). Significantly, the NiFe-LDH catalyst possesses a high faraday efficiency of 88.75% for H2O2 preparation in alkaline media. Moreover, the NiFe-LDH catalyst exhibits excellent OER electrocatalytic property with small overpotential of 210 mV at 10 mA cm?2 and high stability in 1 M KOH solution. On this basis, a new reactor has been designed to electrolyze oxygen and generate hydrogen peroxide. Under the ultra-low cell voltage of 1 V, the H2O2 yield reaches to 47.62 mmol gcat?1 h?1. In order to evaluate the application potential of the bifunctional NiFe-LDH catalyst for H2O2 preparation, a 1.5 V dry battery has been used as the power supply, and the output of H2O2 reaches to 83.90 mmol gcat?1 h?1. The excellent electrocatalytic properties of 2e? ORR and OER make NiFe-LDH a promising bifunctional electrocatalyst for future commercialization. Moreover, the well-designed 2e? ORR-OER reactor provides a new strategy for portable production of H2O2. 相似文献
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Liangtao Yang Liang-Yin Kuo Juan Miguel López del Amo Prasant Kumar Nayak Katherine A. Mazzio Sebastian Maletti Daria Mikhailova Lars Giebeler Payam Kaghazchi Teófilo Rojo Philipp Adelhelm 《Advanced functional materials》2021,31(38):2102939
A known strategy for improving the properties of layered oxide electrodes in sodium-ion batteries is the partial substitution of transition metals by Li. Herein, the role of Li as a defect and its impact on sodium storage in P2-Na0.67Mn0.6Ni0.2Li0.2O2 is discussed. In tandem with electrochemical studies, the electronic and atomic structure are studied using solid-state NMR, operando XRD, and density functional theory (DFT). For the as-synthesized material, Li is located in comparable amounts within the sodium and the transition metal oxide (TMO) layers. Desodiation leads to a redistribution of Li ions within the crystal lattice. During charging, Li ions from the Na layer first migrate to the TMO layer before reversing their course at low Na contents. There is little change in the lattice parameters during charging/discharging, indicating stabilization of the P2 structure. This leads to a solid-solution type storage mechanism (sloping voltage profile) and hence excellent cycle life with a capacity of 110 mAh g-1 after 100 cycles. In contrast, the Li-free compositions Na0.67Mn0.6Ni0.4O2 and Na0.67Mn0.8Ni0.2O2 show phase transitions and a stair-case voltage profile. The capacity is found to originate from mainly Ni3+/Ni4+ and O2-/O2-δ redox processes by DFT, although a small contribution from Mn4+/Mn5+ to the capacity cannot be excluded. 相似文献
3.
In this research, the three‐dimensional structural and colorimetric modeling of three‐dimensional woven fabrics was conducted for accurate color predictions. One‐hundred forty single‐ and double‐layered woven samples in a wide range of colors were produced. With the consideration of their three‐dimensional structural parameters, three‐dimensional color prediction models, K/S‐, R‐, and L*a*b*‐based models, were developed through the optimization of previous two‐dimensional models which have been reported to be the three most accurate models for single‐layered woven structures. The accuracy of the new three‐dimensional models was evaluated by calculating the color differences ΔL*, ΔC*, Δh°, and ΔECMC(2:1) between the measured and the predicted colors of the samples, and then the error values were compared to those of the two‐dimensional models. As a result, there has been an overall improvement in color predictions of all models with a decrease in ΔECMC(2:1) from 10.30 to 5.25 units on average after the three‐dimensional modeling. 相似文献
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通过比较各种软件无线电结构的优缺点,针对既具有交换网络结构又具有分层结构优点的基于交换网络的分层无线电结构方案,提出了部分改进思想。 相似文献
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禹思敏 《电气电子教学学报》2002,24(2):29-32
对数字通信中MPSK系统的调制与解调问题进行了较为的分析,并以8PSK和循环码16PSK系统为例,阐述其调制器电路的逻辑设计方法。在此基础上给出了8PSK系统调制与解调的一种方案,讨论了循环码和自然二进制码16PSK系统的调制器的具体设计过程,该设计方法可应用于一般MPSK系统的逻辑设计。 相似文献
9.
硅光电负阻器件的构成原理与分类 总被引:1,自引:0,他引:1
郭维廉 《固体电子学研究与进展》2002,22(1):120-126
将三端负阻器件与硅光电探测器相结合 ,通过新的构思成功地提出并构成了一类新型光电器件——硅光电负阻器件。文中报道了该器件构成的一般性原理 ,以及依据此构成原理确定的分类方法 相似文献
10.
七号信令网管系统的数据库服务器采用惠普UNIX工作站及SYBASE数据库。由于采集的数据量增大,原先设计的数据库空间不能满足数据存储三个月的要求.因此采用一块外置硬盘对数据库空间进行扩展。详细地介绍了SYBASE数据库空间扩展的全过程。 相似文献