含氯取代基的聚间苯二甲酰间苯二胺的合成与表征

以 2 ,5 -二氯对苯二甲酰氯作为第三单体 ,将其与间苯二甲酰氯、间苯二胺在N ,N -二甲基乙酰胺中进行低温溶液共缩聚反应 ,合成了含氯取代基的聚间苯二甲酰间苯二胺。研究了单体摩尔浓度、反应初始温度、叔胺添加剂种类、第三单体用量等对共聚物相对分子质量的影响 ,并用红外光谱、热重分析等方法对共聚物进行了表征。     

N.m.r. line shape-relaxation correlation analysis of bitumen and oil sands

The first results of the analysis of bitumen and oil sands using the recently developed n.m.r. spingrouping technique are presented. The n.m.r. relaxation experiments were carried out on bitumen, and on natural and dried oil sands samples. The results indicate that the spin-grouping can resolve and quantify several components of the samples studied. The bitumen and bitumen fraction of the oil sands are resolved according to their spin-spin relaxation times into three major groups: solid-like (rigid), solid-like (mobile) and semi-liquid. The water in the oil sands exists in two different environments. Tentatively one environment is assigned to be the bridges between the sand grains, while the other is assigned to be the clay surface. One can conclude that with spin grouping of complex mixtures the decomposition (in which components are resolved according to their dynamic state) is possible. The accuracy of such resolution is of the order of a few per cent.     

Alpha induced reactions on Sn: An experimental study of excitation functions and possible production pathways

In the frame of a systematic study of light ion induced threshold reactions on natural tin (Sn) excitation functions for alpha particles induced reactions are presented in a 12–38 MeV energy domain. Using a stacked foil activation method the following radioisotopes were identified: ¹¹⁶Te, ¹¹⁷Te, ¹¹⁸Te, ¹¹⁹Te, ¹²¹Te, ¹²³Te, ¹¹⁷Sb, ¹¹⁸Sb, ¹²⁰Sb, ¹²²Sb, ¹²⁴Sb, ¹²⁶Sb, ¹¹⁷Sn, ¹¹¹In. The experimental cross sections for these isotopes are presented for the first time in this energy range and a direct comparison with values calculated with the ALICE-IPPE code is discussed. Possible use of these data for production of some isotopes relevant in nuclear medicine is suggested.     

6m焦炉移动设备故障分析及处理

对6m焦炉移动设备运行特点及损坏原因进行了分析，并对6m焦炉移动设备PLC系统，液压系统的故障及其处理方法进行了探讨。     

The radiation crosslinking and scission of ethylene-propylene copolymers studied by solid-state nuclear magnetic resonance

Methyl groups from chain scission and H-crosslinks have been identified by solid-state nuclear magnetic resonance in amorphous ethylene-propylene copolymers containing 23 and 36 mole % propylene after γ-irradiation to 10 MGy at 30°C. G (scission) and G (crosslink) values determined from the n.m.r. spectra and by extraction are in agreement, which suggests that the crosslinks are not clustered. This may differ from the situation in polyethylene where there is a substantial crystalline content. G(S). G(X) and the ratio G(S)/G(X) increase with increasing propylene content of the copolymers.     

运用PLC技术改造385m~2凯利式叶滤机控制系统

根据生产实践 ,结合PLC的技术特点和 385m2 凯利式叶滤机的电气联锁特性 ,阐述了应用PLC技术 ,可进一步提高 385m2 凯利式叶滤机的运转率和自动化水平。     

龙滩工程按正常蓄水位400m方案一次建成效益巨大

2003年11月龙滩工程将实现大江截流，随着工程建设的全面推进，越发显出实施龙滩水电站正常蓄水位400m一次建成方案的重要性和紧迫性。相对分期建设而言，400m水位一次建成，工程效益大、增加投资少、无后期加高过程中的各种技术难题，基本不影响电站的初期发电效益，水轮机设计与运行问题少、机组运行条件好，电站规模效益与社会综合效益巨大，有利于移民安置和库区经济的发展，对国家、地方、企业均十分有利，因此应尽快决策实施400m一次建成方案。     

采用注视控制器实现复杂运动的仿真

注视控制器是3DS MAX软件的众多控件之一，它能使多个物体彼此间产生运动约束。通过使用注视控制器功能，笔者成功制作出八足爬壁式仿生机械昆虫的运动场景动画，并使该仿生机械昆虫各足的行走动作符合机械零件作平面复杂运动时所应遵守的正确运动规律。由此证明，3DS MAX软件注视控制器对正确模拟特殊机械装置的复杂运动可产生极大作用。     

Complex frequency technique for linear and second harmonic optical properties of metallic surfaces

We describe a complex frequency technique for evaluating the linear and quadratic dielectric responses of metal surfaces, illustrated by application to the surface of jellium. The electric susceptibilities are shorter-range functions of the spatial coordinates at complex frequency, whereas their general behaviour is complicated, long-range and highly oscillatory at real frequency. As a result the linear and the second harmonic electric charges induced by an optical perturbation are then numerically easier to calculate at complex frequency. As the functions which characterize the optical behaviour of the metal surface are analytic in the upper complex frequency half-plane, the dielectric response at real frequency can be deduced by analytic continuation from the results at complex frequency. We illustrate and discuss this approach, which should be useful for studying more realistic models of a surface in which the crystal potential is included, and where a direct calculation of the dielectric response is difficult to obtain at real frequency.     

速度密度 10m/s住宅

本文通过一次参加日本《新建筑》国际住宅竞赛的经历，就未来高密度城市环境中住宅的生存状态进行了探讨。并试图用以速度来定义密度的方式探索当私密性与公共交往之间出现不可调和的矛盾时一种新的解决之道。