Ab initio calculations of the NO2 fission for CL-20 conformers

NO₂ fission is regarded to be the most important initial decomposition process of 2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane (CL-20). In this study, four CL-20 conformers based on the ε-CL-20 were obtained after the optimization at m062x/cc-pvtz level, and the bond length, bond order and bond dissociation energy of the N-N bonds were examined to investigate the stability of these bonds. In addition, the rate constants and activation energy of the NO₂ fission were evaluated using the microcanonical variational transition state theory (μVT). The calculation results have shown that N-N bonds in the case of pseudo-equatorial and axial of nitro groups are the most stable and the least stable, respectively, by evaluating the bond length, bond order and minimum energy path (MEP). The NO₂ fission rate constants are affected by not only the stability of N-N bonds but also the repulsion forces from the other nitro groups, and the fission process for pseudo-equatorial positioning of nitro groups is easier to be accelerated due to the increase of the repulsion forces. The decomposition of CL-20 conformer may mainly originate from the fission of the pseudo-equatorial positioning of nitro groups, especially for CL-20 III conformer because of the significant low activation energy.     

Can Fusion and Fission Breeding Help Civilization Survive?

As apparent from the title, this author feels that civilization faces a real threat, one which will become obvious and serious within the lifetimes of many readers of this article. This threat is not global warming, but lack of affordable energy. We take for granted turning on a light, or adjusting our thermostats in winter or summer, or filling our cars gas tank; and lose sight of the fact that there are huge and complicated industrial systems which make this possible. But as we run out of petroleum and natural gas, and worry about the environmental and climatic effects of burning coal on the required scale, how can this continue? This paper makes the case that breeding nuclear fuel, by both fusion and fission, is the only way our civilization as we know it, can continue beyond the next half century or so.     

具有多值约束的线性递归查询的有效计算

本文给出三个算法,分别用于把给定的右线性、左线性或左-右线性递归程序改写为一组更有效的规则.与Ullman等人的变换算法不同,本文的算法允许查询的初始约束可以是含任意多个约束元组的集合,而不必是单值的;这样,本文的算法不仅可以用于查询的求值,而且也可以用于子目标的处理.变换算法的正确性和变换后规则的有效性也在本文简略讨论.     

应用磷灰石裂变径迹研究大民屯凹陷的古地温

为深刻认识辽河盆地古地温特征，利用裂变径迹分析方法，对大民屯凹陷钻井岩心中19块磷灰石样品的裂变径迹年龄和长度做了测试。结果表明，随井深增加，径迹年龄和平均径迹长度有减少、变短的显著趋势，ES3^4地层磷灰石裂变径迹表观年龄比地层年龄年轻得多，说明沉积后曾长时间处于退火带中，退火带古地温为74～130℃，有效加热时间为4l～45Ma，2300～4000m深度地层处于退火过渡带。将径迹长度分布特征与地史、热史模拟结果相结合，认为该区在ES4段末经历一次短时间迅速增温后，ES3^1亚段存在一个区域抬升降温的热事件过程，其后地层稳定下降，沉降幅度小、沉积物较薄，温度增加缓慢，古地温梯度高于今地温梯度，对生、排烃较为有利。     

Effect of Water Vapor on the Release of Fission Gases from Uranium Oxycarbide in High-Temperature, Gas-Cooled Reactor Coated Fuel Particles

The hydrolysis of uranium oxycarbide (UCO) was studied by injecting water vapor into a fuel element containing a known number of high-temperature, gas-cooled reactor (HTGR) coated particles with exposed fuel kernels. The experiments were conducted in the High Flux Isotope Reactor (HFIR) at temperatures between 700° and 1000°C, a system pressure of 200 kPa, and partial pressures of water vapor between 21 and 199 Pa. The general sequential response of the exposed fuel kernels to water vapor addition consisted of (1) a rapid release of stored fission gas with a concomitant increase in the steady-state release and (2) a period of constant steady-state release. Upon cessation of the addition of water vapor, a decline in the release to prehydrolysis values generally occurred. The release of stored fission gas was dependent on the square of the partial pressure of water vapor. The ratio of the constant steady-state release to the prehydrolysis value was independent of the partial pressure of water vapor. The time constant for the decline in the release was the same in all of the hydrolysis tests.     

正态分布属性数据集上的Skyline查询

Skyline查询适用于多目标决策、数据挖掘等领域。以往的研究工作主要关注确定型数据集,少数针对不确定型数据集的研究处理的也多是离散型不确定数据。为此,定义属性呈连续型分布的不确定数据集,并给出一种针对该种数据集的Skyline查询算法,利用索引和分治思想解决其Skyline查询问题。实验结果表明,该算法可以在牺牲少量精度的情况下提高查询效率。     

基于层次社会组织目标的需求过程建模

将社会组织结构抽象为递归的社会组织域树,其顶层目标即为社会组织总体目标,总体目标层层分解为社会子组织域目标,从层次化的社会组织目标构建软件系统需求目标分解树,进而构建软件系统需求,并用层次着色Petri网对软件系统需求过程进行形式化建模,无缝连接社会组织目标与软件系统需求,为软件系统需求分析提出了一种自然、直观的需求过程建模方法.     

基于矩阵谱的反应堆屏蔽仿真计算

研究了热中子反应堆屏蔽准确性优化设计问题.由于传统的反应堆屏蔽计算并未考虑引发裂变的中子对裂变能谱的影响,使得燃耗加深时仿真计算结果与实际情况差别较大.针对上述问题,提出从与入射中子能量相关的Maxwell谱出发,对入射中子的能量进行分群,构造出矩阵谱,然后确定了仿真计算中对裂变中子能量的抽样步骤,并在中子输运计算软件MCNP程序上进行了仿真计算.结果表明,根据矩阵谱计算得到的结果能够反映出燃耗变化对屏蔽计算的影响,能够为反应堆屏蔽设计提供更为准确的依据.     

基于微课的翻转课堂教学实践

本文以C语言程序设计课程中的递归程序教学为例,论述了基于微课开展翻转课堂教学的教学设计及实施方法。