Relationship between the adhesion properties of UV-curable alumina suspensions and the functionalities and structures of UV-curable acrylate monomers for DLP-based ceramic stereolithography

Digital light processing (DLP)-based ceramic stereolithography has attracted significant attentions due to the high printing speed and high dimensional accuracy of DLP printers. However, undesired dropping of unfinished ceramic parts during printing, owing to inadequate adhesion between the first cured layer and the substrate of the building platform, still remains a challenge. In this study, the relationship between the adhesion properties of ultraviolet (UV)-curable alumina (α-Al₂O₃) suspensions and the functionalities and structures of UV-curable acrylate monomers was investigated. With an increase in the proportions of monofunctional monomers, the adhesion abilities of UV-curable alumina suspensions enhanced because of reduced volume shrinkage, however, inferior curing performances were observed due to a decrease in the double bond densities. Furthermore, the large-volume branched chain structures in monofunctional monomers and ethyoxyl groups in polyfunctional monomers effectively decreased the volume contraction, improving the adhesion performances of UV-curable alumina suspensions and facilitating the conversion of double bonds to provide excellent curing properties, further guaranteeing strong adhesion of these suspensions to the substrate.     

面曝光快速成形系统升降工作台运动精度研究

介绍了面曝光快速成形实验系统的基本原理,构建了由运动控制卡、驱动器、精密滚珠丝杠、直线导轨等组成的升降工作台,并对其运动精度进行了测试和评定．工作台向下进给时,定位精度为10．9μm,单向重复定位精度为10．8μm;工作台向上进给时,定位精度和单向重复定位精度都为7．6μm．测试结果表明,该系统能够满足制作小尺寸零件的精度要求．     

绘图仪式高速激光树脂3D打印设备研制

为了进一步探索3D打印实现方法,提高精度和效率,在绘图仪的结构基础上,结合光固化立体打印技术(SLA)的原理,设计了一种用于树脂材料的绘图仪式3D打印设备(SLP),它拥有绘图仪式的运动结构,激光及聚焦部分可直接做xy二维运动.相对于SLA技术,SLP大幅减小了焦距,所以对光源的要求更低.相比SLA和数字光处理技术(DLP),SLP加工幅面更容易扩大.     

台式快速成型设备扫描系统研制

介绍了在台式快速成型制造系统研制中，为稳定系统性能、降低设备造价所采取的技术措施：通过对扫描方式的比较，选择了X－Y二维导轨式扫描方式；用普通紫外灯光源取代激光光源；基于锥度光纤传输、聚焦的光路系统等技术。     

光敏树脂对快速原型件表面质量的影响

为评价光敏树脂HSL 1的性能,比较了HSL 1和光敏树脂SL 7545的特性参数、力学性能和黏度,结果显示两种光敏树脂性能相近。研究了两种光敏树脂对快速原型件表面质量的影响,对快速原型件表面粗糙度值的研究表明:快速原型件的上水平表面质量最好,下水平表面质量最差,侧表面质量受倾斜角度影响;且快速原型件表面质量受到光敏树脂组分、透射深度、单层固化强度和黏度的影响。     

基于增材制造技术的空心涡轮叶片精准成形控制

目的 基于光固化快速成形工艺,将一体化陶瓷铸型技术与数值模拟技术相结合,采用型腔反变形方法补偿金属液凝固收缩,实现高复杂空心涡轮叶片的型面精准成形控制。方法 通过数值模拟分析了叶片各方向(叶宽、叶长和叶厚)的凝固变形规律,并建立了各截面的位移场模型。通过仿真迭代补偿凝固收缩,修正了叶身外型面,完成了叶片CAD模型重构。基于光固化快速精铸技术,快速制作了一体化铸型,并完成了叶片浇注实验。结果 对补偿前后叶片叶身外型面偏差进行统计可知,叶身主要部位偏差明显降低,尾缘偏差由−0.335 mm降低至−0.136 mm,前缘偏差由−0.246 mm降低至−0.111 mm,验证了该技术在叶片型面精度控制方面的有效性。结论 实现了涡轮叶片型面精度的有效控制,为高精度空心涡轮叶片的快速制造提供了新的途径。     

光固化成形系统激光光斑光强分布检测方法研究

激光束的模式及光强分布对光固化成形制件质量的影响很大。本文采用针孔矩阵扫描方法。检测激光束投射在工作平面上的光斑,并经过数据处理获得光斑的二维和三维的光斑分布图像。该方法获得的数据既可对光斑进行定量分析也可用于定性分析。     

Fabrication of zirconia all-ceramic crown via DLP-based stereolithography

Zirconia ceramics have shown a wide applicable prospect in dental prosthetics because it possesses excellent mechanical performance and biocompatibility. The rheological behavior and curing properties of zirconia stereolithography slurry were studied, as well as the microstructure of the green, pyrolyzed, and sintered body. Variquat CC-42 NS was proved to be effective for zirconia powder dispersing in photocurable resin (SP-RC700). The curing characteristic of slurry showed that the depth of penetration tended to increase with the solid loading. Finally, the zirconia all-ceramic crowns were fabricated via DLP-based stereolithography printer. Results showed that the particles were evenly distributed in the cured resin matrix without obvious agglomeration, and the interlayered structure disappeared after binder burnout. The sample with a major crystalline phase of tetragonal zirconia and a porosity of 10(1)% were obtained after sintering at 1550°C.     

织构PNN-PZT陶瓷的光固化成型制备及其电学性能研究

为高效制备织构压电陶瓷,以球状Pb(Ni_1/3Nb_2/3)O₃-PbZrO₃-PbTiO₃ (PNN-PZT) 为基体粉体,片状BaTiO₃ （BT）为模板粉体,采用光固化成型技术代替传统流延技术制备织构压电陶瓷。研究了粉体形貌对打印浆料流动性的影响、浆料的光敏参数以及不同BT含量织构陶瓷的晶体结构和电学性能。结果表明,球状粉体浆料具有低黏度的特性,能够有效提高打印浆料的固含量,最大固含量可达86%（质量）。此时陶瓷浆料的临界曝光量与透射深度分别为127.5 mJ/cm²和21.1 μm。打印后的PNN-PZT-BT陶瓷沿[00l]_c方向生长,BT模板粉体含量从1%增长到5%,陶瓷的织构度由42%增到92%。当BT含量为3%时,样品具有最高的压电常数d₃₃=1047 pC/N。与传统的流延法相比,SLA技术的工艺优势在于制备周期短,稳定性高,能够有效降低织构陶瓷的制备难度。