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双层包覆红磷的制备及阻燃聚丙烯的研究
引用本文:赵玉叶,鲍远志,翁世兵,柴多里. 双层包覆红磷的制备及阻燃聚丙烯的研究[J]. 广州化工, 2013, 0(24): 73-75
作者姓名:赵玉叶  鲍远志  翁世兵  柴多里
作者单位:[1]合肥工业大学化工学院,安徽合肥230009 [2]六安市捷通达化工有限责任公司,安徽六安237158
摘    要:采用沉淀法制备双层包覆红磷(DERP),通过FESEM、XPS、TG、吸湿性测试对其进行了表征。结果表明:红磷表面形成均匀的包覆层,包覆率达到97.18%,包覆后的红磷吸湿性也得到较大改善,着火点提高到430℃。将阻燃剂DERP添加到聚丙烯中,质量分数为5%时,阻燃级别可达到UL94V-0级。

关 键 词:双层包覆红磷  阻燃等级  聚丙烯

Preparation of Double Encapsulated Red Phosphorus and its Flame- Retardant Application in PP Composites
Affiliation:ZHAO Yu - ye1 , BAO Yuan - zhi2, WENG Shi - bing2, CHAI Duo - li1 ( 1 School of Chemical Engineering, Hefei University of Technology, Anhui Hefei 230009 ; 2 Luan Keruida New Materials Co. , Ltd. , Anhui Lu'an 237158, China)
Abstract:The Double Encapsulated Red Phosphorus (DERP) which was prepared by deposition sedimentation method was investigated by FESEM, XPS, and TG analysis means. The result indicated that an uniform layer of encapsulation was formed, 97.18% of the red phosphorus was encapsulated, the water absorption rate was lowered apparently and the ignition point of red phosphorous was improved to 430 ℃. Adding the DERP to the polypropylene (PP) for fire retardant, the flame retardant reached UL 94 V-0 class after adding 5% DERP.
Keywords:DERP  flame retardant rating  PP
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