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ZnO/O3工艺降解水中微量有机物的研究
作者姓名:赵大鹏  徐贞贞  王洪蕾
作者单位:1. 宁波钢铁有限公司,能源部,浙江,宁波,315807
2. 哈尔滨工业大学,市政环境工程学院,黑龙江,哈尔滨,150090
3. 济南市水业集团有限责任公司,山东,济南,250002
摘    要:以实验室制备的粉末氧化锌(ZnO)为催化剂,考察了ZnO/O3工艺去除水中有机物的效能.采用总有机碳(TOC)指标反映水中有机污染物的含量.结果表明:臭氧投量为1 mg/L、ZnO投量为300 mg/L时,反应60 min后ZnO-O3工艺对TOC的去除率为46%,比单独臭氧化提高了1倍;反应温度明显影响该工艺对有机物的降解效果,在水温为5,10,20和25 ℃时,TOC的去除率分别为17.5%,31.5%,45.9%和51.3%.臭氧浓度和催化剂投量的增加,可以提高TOC的氧化降解效率.

关 键 词:氧化锌  催化臭氧化  总有机碳  饮用水

Study on ZnO/O3 process for degradation of organics in water
Authors:Zhao Dapeng  Xu Zhenzhen  Wang Honglei
Affiliation:Zhao Dapeng1,Xu Zhenzhen2,Wang Honglei3(1.Sources of Energy Department,Ningbo Steel Co.,Ltd.,Ningbo 315807,China,2.School of Municipal , Environmental Engineering,Harbin Institute of Technology,Harbin 150090,3.Jinan Water Supply Limited Liability Company,Jinan 250002,China)
Abstract:As a catalyst,the powdered ZnO was applied to investigate the efficiency of ZnO/O3 process in degrading organic compounds in raw water.The concentration of organic compounds was characterized by TOC(total organic carbon).Results showed that TOC removal efficiency in ZnO-O3 system was 46% with the initial ozone concentration of 1 mg/L and ZnO dosage of 300 mg/L,about two times as that of ozonation only.Water temperature influenced the TOC degradation obviously,the removal rates of TOC in the ZnO/O3 process w...
Keywords:zinc oxide  catalytic ozonation  TOC  drinking water  
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