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A liquid-feed solid polymer electrolyte direct methanol fuel cell operating at near-ambient conditions
Affiliation:1. Solid State and Structural Chemistry Unit, Indian Institute of Science, Bangalore 560012, India;2. Department of Chemistry, Bedson Building, The University, Newcastle upon Tyne, NE1 7RU, UK;1. School of Food Science and Engineering, South China University of Technology, Guangzhou 510640, China;2. Shenzhen Key Laboratory of Polymer Science and Technology, College of Materials Science and Engineering, Shenzhen University, Shenzhen 518060, China;3. Institute of Green Chemistry and Energy, Graduate School at Shenzhen, Tsinghua University, Shenzhen 518055, China;1. Centro de Nanociencias y Nanotecnología, Universidad Nacional autónoma de México, Ensenada, 22860, Mexico;2. Tomsk Polytechnic University, Tomsk, 634050 Russia;3. Tomsk State University, Tomsk, 634050 Russia;5. Universidad Autónoma de Baja California, Ensenada, 22860, Mexico;6. CONACYT Research Fellow at Centro de Nanociencias y Nanotecnología, UNAM, Ensenada, 22860, Mexico;7. Institute of Catalysis and Petroleum Chemistry (ICP), CSIC, 28049 Madrid, Spain;8. Centro de Ciencias Aplicadas y Desarrollo Tecnológico, Universidad Nacional autónoma de México, Cd. Mx, 04510, Mexico;1. Department of Chemistry, Milan University, via Golgi 19, 20133 Milan, Italy;2. Institute of Nanotechnology and Karlsruhe Nano Micro Facility (KNMF), Karlsruhe Institute of Technology, Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany;1. Department of Behavioural Ecology, Institute of Ecology and Evolution, University of Bern, Hinterkappelen, Switzerland;2. University of Groningen, Centre of Behaviour and Neurosciences, Groningen, The Netherlands;1. Latin-American Institute of Life and Nature Sciences, Federal University of Latin-American Integration (UNILA), 85.867-900, Foz do Iguaçu, PR, Brazil;2. Federal University of Technology-Paraná (UTFPR), 86.036-370, Londrina, PR, Brazil;3. Desenvolvimento de Materiais Inorgânicos com Terras Raras (DeMITeR), Laboratório de Materiais Fotoluminescentes (LAMAF), Institute of Chemistry, Federal University of Uberlândia (UFU), 38.400-902, Uberlândia, MG, Brazil
Abstract:Results on the performance of a 25 cm2 liquid-feed solid polymer electrolyte direct methanol fuel cell (SPE-DMFC), operating under near-ambient conditions, are reported. The fuel cell can sustain a load current density of 100 mA cm−2 with an output voltage of c. 450 mV at 90°C with 2 M aqueous methanol and air-fed cathode at near-ambient pressures with a catalyst loading of 5 mg cm−2 of Pt. Preliminary data on the performance of a liquid-feed SPE-DMFC stack comprising two 25 cm2 cells are also reported. These data are sufficient to suggest that further developmental work on liquid-feed SPE-DMFCs operating under near-ambient conditions (0 barg O2 at 90°C) is well worthwhile.
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