不饱和烃硅氢加成催化剂固载化研究进展

综述了各类负载过渡金属的催化剂体系及其在不饱和烃硅氢加成反应中的应用。负载过渡金属的催化剂具有良好的可回收性和选择性，研究主要集中在开发价廉、使用安全、环境友好和高催化性能的活性炭、氧化物或有机聚合物等负载过渡金属催化剂，并取得很好的结果。

Hydrosilylation of unsaturated hydrocarbons promoted by supported catalyst

The scope of hydrosilylation of unsaturated hydrocarbons in synthesis has greatly expanded because of the wide array of catalyst systems that are now available for these reactions. Besides homogeneous catalysis that retained most attention in the past decades, new catalyst systems based on supported transition metals have recently emerged, that enabled outstanding achievement in recycling and selectivity. Also, investigations have focused on the development of friendly, cost-effective process, utilization of safe and inexpensive supported catalysts instead of homogenous catalysts have attained high synthetic efficacy. This review covered the development and application of these new hydrosilylation catalyst systems.