Epoxidation of cyclohexene on Nb-containing meso- and macroporous materials |
| |
Authors: | Izabela Nowak Beata Kilos Maria Ziolek Anna Lewandowska |
| |
Affiliation: | Faculty of Chemistry, A. Mickiewicz University, Grunwaldzka 6, PL-60-780, Poznan, Poland |
| |
Abstract: | Various niobium-containing meso- and macroporous materials were prepared and characterised by means of XRD and H2-TPR techniques, scanning electron microscopy (SEM), and sorption measurements. They were tested in the liquid phase oxidation of cyclohexene to epoxide with hydrogen peroxide. The effect of various parameters such as a nature of solvent, material structure, atmosphere on the activity and selectivity of the reaction was studied. NbMCM-41 and NbSM-2 materials are highly active in the epoxidation. |
| |
Keywords: | NbMCM-41 NbSM-1 NbSM-2 Epoxidation Cyclohexene |
本文献已被 ScienceDirect 等数据库收录! |
|