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Co /SBA-15催化氧化石蜡的研究
引用本文:郭泽军,李会鹏,沈健,赵华.Co /SBA-15催化氧化石蜡的研究[J].石油炼制与化工,2009,40(7):47-50.
作者姓名:郭泽军  李会鹏  沈健  赵华
作者单位:辽宁石油化工大学 辽宁石油化工大学 辽宁石油化工大学
摘    要:实验以52号石蜡为原料,采用Co /SBA-15为催化剂,用空气作氧化剂,对石蜡氧化进行了研究。考察了反应温度、反应时间、空气流量等工艺条件的影响。实验结果表明,Co2O3最佳负载量为15%,在氧化温度140℃、氧化时间5h、空气流量0.6L/min的最佳反应条件下可得到色泽浅、气味轻、酸值较高的氧化石蜡产品。

关 键 词:催化剂  酸值  SBA-15  氧化  
收稿时间:2008-10-30

STUDY ON THE CATALYTIC OXIDATION OF PARAFFIN WAX OVER Co/SBA-15 CATALYST
Guo Zejun,Li Huipeng,Shen Jian,Zhao Hua.STUDY ON THE CATALYTIC OXIDATION OF PARAFFIN WAX OVER Co/SBA-15 CATALYST[J].Petroleum Processing and Petrochemicals,2009,40(7):47-50.
Authors:Guo Zejun  Li Huipeng  Shen Jian  Zhao Hua
Abstract:Study on the oxidation of paraffin wax was carried out by using 52# wax as raw material, Co/SBA-15 as catalyst and air as oxidant. The effects of reaction temperature, reaction time and air flux on the oxidation of wax were investigated. The experimental results indicated that under the optimal reaction conditions of using a Co/SBA-15 catalyst with an optimal Co2O3 loading of 15%, an oxidation temperature of 140℃, an oxidation time of 5h and an air flux of 0.6 L/min, a high acid number, light color and less odor oxidized wax was obtained.
Keywords:catalyst  acid number  SBA-15  oxidation  
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