Diels-Alder Reactions of the [60]Fullerene: From Regularly Functionalized Carbon Spheres to Cyclophanes |
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| Authors: | Josef Maynollo Bernhard Kräutler |
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| Affiliation: | University of Innsbruck , Institute of Organic Chemistry , Innsbruck, A-6020, Austria |
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| Abstract: | Abstract Diels-Alder reactions allow the regioselective preparation of various derivatives of the [60]fullerene (1) with exohedral functionalization. A symmetric sixfold [2+4]-cycloaddition of 1,3-dienes to 1 opens direct synthetic access to hydrocarbons with a novel cyclophane structure. |
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