An Experimental Measurement of Effective Diffusion Distance for the Sintering of Ceramics |
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Authors: | Tiandan Chen Ian Nettleship Richard J McAfee Tom R Hinklin Kevin G Ewsuk |
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Affiliation: | Department of Mechanical Engineering and Materials Science, University of Pittsburgh, Pittsburgh, Pennsylvania 15261; Sandia National Laboratories, Albuquerque, New Mexico 87185-0352 |
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Abstract: | The traditional models of sintering predict a pronounced dependence of densification rate on the scale of the microstructure as measured by the grain size. This study evaluates the grain size exponent for densification during isothermal sintering of an aggregated nanocrystalline zirconia powder, and for a submicrometer alumina powder. The results gave grain size exponents that are much higher than those anticipated for the expected sintering mechanisms. Furthermore, microstructural analysis showed that this overestimate of the exponent could be due to the spatial heterogeneity in the microstructure on the scale of the diffusion distance. To assess this issue, pore boundary tessellation was used to determine a new measurement of effective diffusion distance that takes into account the local spatial arrangement of pores. This measurement gives exponents much closer to those expected for the sintering of tetragonal zirconia by volume diffusion, and for the sintering of the alumina by grain-boundary diffusion. |
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