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有机卤代反应中高效卤化试剂的应用及发展
引用本文:郑宾国,李雪辉,耿卫国,张磊,王乐夫. 有机卤代反应中高效卤化试剂的应用及发展[J]. 天然气化工, 2005, 30(2): 70-74
作者姓名:郑宾国  李雪辉  耿卫国  张磊  王乐夫
作者单位:华南理工大学化学工程系,广州,510640
基金项目:广东省科技攻关项目(No .2 0 0 2B2 1 60 6,No . 2 0 3C3 3 50 3 ),广东省自然科学基金(No .0 3 1 41 9)资助
摘    要:卤代反应是有机合成中的一类重要反应,选择合适的卤化试剂是实现该类反应的关键,也是目前研究的热点之一。本文对近年来在高效卤化试剂研究方面取得的进展进行了综述,介绍了系列高效卤化剂在卤化取代反应、卤化加成反应等方面的应用。具体评述了不同卤化试剂的优缺点并展望了卤化试剂的发展趋势。

关 键 词:卤化反应  卤化取代  卤化加成  卤化试剂
文章编号:1001-9219(2005)02-70-05
修稿时间:2004-12-23

Application and Development of High Efficiency Halogenating Agents
ZHENG Bin-guo,LI Xue-hui,GENG Wei-Guo,ZHANG Lei,WANG Le-fu. Application and Development of High Efficiency Halogenating Agents[J]. Natural Gas Chemical Industry, 2005, 30(2): 70-74
Authors:ZHENG Bin-guo  LI Xue-hui  GENG Wei-Guo  ZHANG Lei  WANG Le-fu
Abstract:Halogenating reaction is one of the most important reactions in organic synthesis and the choosing of appropriate halogenating reagent is the hot spot of this field and plays an important role in achieving this kind of reaction. In this paper, research progress in the studying of high efficiency halogenation agent in recent years was reviewed and the application of a series of high efficiency halogenating reagents in halogenating substitution reaction and halogenating addition reaction were introduced. The advantage and disadvantage of different halogenating agents were discussed and the developing tendency was prospected.
Keywords:halogenating reaction  halogenating addition reaction  halogenating substitution reaction  halogenating reagent
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