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Thermodynamic evaluation of Cu– system based on newly determined Gibbs energy of formation of |
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| Authors: | T Noda K Oikawa S Itoh M Hino T Nagasaka |
| Affiliation: | aGraduate School of Environmental Studies, Tohoku University, Sendai 980-8579, Japan;bGraduate School of Engineering, Tohoku University, Sendai 980-8579, Japan;cGraduate School of Environmental Studies, Tohoku University, Sendai 980-8579, Japan |
| Abstract: | Thermodynamic evaluation of Cu–Cu3P system has been conducted by applying subregular solution model with Gibbs energy of Cu3P formation that was newly determined by means of triple Knudsen cell mass spectrometry. Both the calculated vapor pressure of phosphorus and phase diagram of Cu–P system are excellently consistent with the literature data in the composition range of Cu–Cu3P, indicating that there is no significant thermodynamic inconsistency between the present work based on the Gibbs energy of Cu3P formation determined and the literature data. |
| Keywords: | Melting treatment process Subregular solution model Cu– P alloy Mass spectrometry Cu3P |
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