| 环【8】吡咯及其衍生物的一锅法合成、表征及光谱分析 |
| |
| 引用本文： | 陈芳军,黄可龙,徐海,许慧. 环【8】吡咯及其衍生物的一锅法合成、表征及光谱分析[J]. 广州化工, 2009, 37(1): 61-64 |
| |
| 作者姓名： | 陈芳军 黄可龙 徐海 许慧 |
| |
| 作者单位： | 中南大学化学化工学院,湖南,长沙,410083 |
| |
| 摘 要： | 一锅法合成了环【8】吡咯及其衍生物环【6]吡咯和环[7】吡咯，用正交实验获得了合成的最佳条件，使产率分别达到32％，20％，9％，对三个化合物进行了核磁共振氢谱、核磁共振碳谱、元素分析表征，研究了环[n】吡咯（n=6，7，8）的紫外可见吸收光谱和荧光发射光谱。
|
| 关 键 词： | 环 吡咯(n=6,7,8) 合成与表证 紫外可见光谱 荧光光谱 |
One-Spot Method Synthesis and Characterization and Spectrum Analysis of Cyclo[8]pyrrole and its Derivatives |
| |
| CHEN Fang-jun,HUANG Ke-long,XU Hai,XU Hui. One-Spot Method Synthesis and Characterization and Spectrum Analysis of Cyclo[8]pyrrole and its Derivatives[J]. GuangZhou Chemical Industry and Technology, 2009, 37(1): 61-64 |
| |
| Authors: | CHEN Fang-jun HUANG Ke-long XU Hai XU Hui |
| |
| Affiliation: | School of Chemistry and Chemical Engineering;Central South University;Hunan Changsha 410083;China |
| |
| Abstract: | Cyclo[8]pyrrole and its two derivatives(cylo[6]pyrrole and cyclo[7]pyrrole) were synthesized by one spot method.The optimum processing conditions were found in orthogonal experiments,bringing the yields were 32 %,20 %,9 %,respectively.The structures of the three compounds were characterized by 1HNMR,13 C NMR and elemental analysis.The UV-vis spectrums and fluorescence spectrums of the three compounds were studied. |
| |
| Keywords: | cyclo pyrrole （n=6, 7, 8） synthesis and characterization UV-vis spectrums fluorescence spectrums |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
|
