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层状Ni-Mn基锂离子电池正极材料进展
引用本文:叶尚云,张平伟,乔芝郁.层状Ni-Mn基锂离子电池正极材料进展[J].稀有金属,2005,29(3):328-338.
作者姓名:叶尚云  张平伟  乔芝郁
作者单位:1. 北京科技大学物理化学系,北京,100083
2. 个旧圣比和实业有限公司,云南,个旧,661000
基金项目:国家高技术研究发展计划(863计划)(2003AA32X270)资助项目
摘    要:层状Ni—Mn基锂离子电池正极材料具有层状结构镍酸锂(LiNiO2)的高比容量以及尖晶石型结构锰酸锂(LiMn2O4)的高安全性、低价格等特点,是最有可能代替或部分代替LiCoO2的新型正极材料用于小型锂离子电池,同时也可望用作低成本、高安全性和大容量动力型锂离子电池的正极材料。本文综述了层状Li—Ni—Mn—O系化合物和LiNi1/3Mn1/3Co1/3O2的合成工艺、结构特点和电化学性能,阐述了层状Ni—Mn基锂离子电池正极材料的发展、研究开发现状和应用前景。

关 键 词:层状结构Ni—Mn基化合物  正极材料  锂离子电池
文章编号:0258-7076(2005)03-0328-11

A Review on Novel Lithium-Ion Cathode Materials Based on Layered Nickel Manganese Oxides
Ye Shangyun,Zhang Pingwei,Qiao Zhiyu.A Review on Novel Lithium-Ion Cathode Materials Based on Layered Nickel Manganese Oxides[J].Chinese Journal of Rare Metals,2005,29(3):328-338.
Authors:Ye Shangyun  Zhang Pingwei  Qiao Zhiyu
Affiliation:Ye Shangyun~
Abstract:Lithium nickel manganese oxide with layered crystal structure is one of the most promising cathode materials for the next generation of lithium-ion cells, especially for high power Li-ion batteries, due to the high safety, low cost and excellent electrochemical properties of manganese-based materials. The syntheses, structure, properties and applications of the Li(Ni,Mn,Co)O_2 and their derivatives were reviewed in this paper.
Keywords:layered nickel-manganese-based compounds  cathode materials  lithium-ion battery
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