Direct Transesterification/Isomerization/Methoxycarbonylation of Various Plant Oils |
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| Authors: | Guido Walther Andreas Martin Angela Köckritz |
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| Affiliation: | 1. Leibniz Institute for Catalysis at the University of Rostock (LIKAT), Albert-Einstein-Str. 29A, 18059, Rostock, Germany
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| Abstract: | A selection of plant oils was catalytically transferred into 1,19-nonadecanedioate by a direct transesterification, isomerization and methoxycarbonylation under mild conditions using Pd/o-C6H4(CH2P t Bu2)2. Additionally, sulfuric acid was demonstrated as being able to substitute methane sulfonic acid as co-catalyst without any significant loss of activity and selectivity. |
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| Keywords: | Palladium Methoxycarbonylation Plant oil ‐Diester Sulfuric acid |
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