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玉米秸秆稀酸蒸汽爆破协同作用机制研究
引用本文:贾天宇,廖克俭,佟名友,王鑫,李秀铭. 玉米秸秆稀酸蒸汽爆破协同作用机制研究[J]. 当代化工, 2011, 0(12): 1224-1227,1230
作者姓名:贾天宇  廖克俭  佟名友  王鑫  李秀铭
作者单位:辽宁石油化工大学;抚顺石油化工研究院
摘    要:以玉米秸秆原料,进行蒸汽爆破处理,比较了水蒸气蒸爆、稀酸和稀酸蒸爆3种预处理方法,通过对3种预处理过程中米秸秆纤维组分变化、纤维素和半纤维素降解产物和玉米秸秆结构分析以及酶解试验,探讨稀酸蒸汽爆破的协同作用机制.结果表明,稀酸蒸爆协同作用包括稀酸的软化和蒸汽爆破的活化两种机制:一是通过稀酸脱除大部分的半纤维素破坏了半纤...

关 键 词:玉米秸秆  蒸汽爆破  预处理  木质纤维素

Research on Synergism of Acid-catalyzed Steam Explosion of Corn Stalk
JIA Tian-yu,LIAO Ke-jian,TONG Ming-you,WANG Xing,LI Xiu-ming. Research on Synergism of Acid-catalyzed Steam Explosion of Corn Stalk[J]. Contemporary Chemical Industry, 2011, 0(12): 1224-1227,1230
Authors:JIA Tian-yu  LIAO Ke-jian  TONG Ming-you  WANG Xing  LI Xiu-ming
Affiliation:1(1.Liaoning Shihua University,Liaoning Fushun 113001,China; 2.Fushun Research Institute of Petroleum and Petrochemicals,Liaoning Fushun 113001,China)
Abstract:Using corn stalk as raw material, three pretreatments including water vapor steam explosion, dilute acid catalysis and dilute acid-catalyzed steam explosion were carried out in order to investigate synergy effect of steam explosion and dilute acid catalysis. For the purpose, effects of acid-catalyzed steam explosion on corn stalk were analyzed and characterized, such as composition, structure, property of the matter, forming degradable products after pretreatments and enzymatic hydrolysis. The results show that the positive effect of acid-catalyzed steam explosion attributes to the synergistic interactions of acid-softening and steam activation. First, the hemicellulose removal with acid can break the interaction between cellulose and ligin, and soften lignocellulosic structure. Second, steam explosion of acid- softened matter can lead to the forming of an active supramolecular structure, which can increase the accessibility of cellulase to celluloses.
Keywords:Corn stalks  Steam explosion  Pretreatment  Lignocellulose
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