Magnesiothermic Reduction Process Applied to the Powder Production of U(Mo) Fissile Particles |
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Authors: | Guillaume Champion Jérôme Allenou Mathieu Pasturel Henri Noël François Charollais Marie‐Christine Anselmet Xavière Iltis Olivier Tougait |
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Affiliation: | 1. Institut des Sciences Chimiques de Rennes, UMR‐ 6226, CNRS‐Université de Rennes 1 Campus de Beaulieu, Rennes 35042, France;2. CEA, DEN, DEC, Cadarache Saint‐Paul‐Lez‐Durance, 13108, France |
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Abstract: | Uranium‐molybdenum alloy powders are obtained by a new synthetic route deriving from the Kroll process which avoids a “melting‐solidification” step. This alternative process consists in the reduction of uranium dioxide by magnesium in presence of Mo in a sealed Mo crucible heated at temperatures ranging from 750 to 1100 °C for dwell periods ranging from 12 to 48 h. An appropriate quenching allows the retention of the high temperature bcc‐form γ–U(Mo). The side products are easily removed by a soaking into a diluted hydrochloric acid solution under sonication. The agglomerates have a typical size in the range 10–200 µm, with an irregular shape. They display even at the periphery equiaxed grains with homogeneous distribution of Mo. Small closed porosity, which seems to be preferentially located at the grain boundaries corresponds to roughly 2% of the volume fraction. |
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