Reconstruction of Conformal Nanoscale MnO on Graphene as a High‐Capacity and Long‐Life Anode Material for Lithium Ion Batteries |
| |
Authors: | Yongming Sun Xianluo Hu Wei Luo Fangfang Xia Yunhui Huang |
| |
Affiliation: | State Key Laboratory of Material Processing and Die & Mould Technology, College of Materials Science and Engineering, Huazhong University of Science and Technology, Wuhan 430074, P. R. China |
| |
Abstract: | To tackle the issue of inferior cycle stability and rate capability for MnO anode materials in lithium ion batteries, a facile strategy is explored to prepare a hybrid material consisting of MnO nanocrystals grown on conductive graphene nanosheets. The prepared MnO/graphene hybrid anode exhibits a reversible capacity as high as 2014.1 mAh g?1 after 150 discharge/charge cycles at 200 mA g?1, excellent rate capability (625.8 mAh g?1 at 3000 mA g?1), and superior cyclability (843.3 mAh g?1 even after 400 discharge/charge cycles at 2000 mA g?1 with only 0.01% capacity loss per cycle). The results suggest that the reconstruction of the MnO/graphene electrodes is intrinsic due to conversion reactions. A long‐term stable nanoarchitecture of graphene‐supported ultrafine manganese oxide nanoparticles is formed upon cycling, which yields a long‐life anode material for lithium ion batteries. The lithiation and delithiation behavior suggests that the further oxidation of Mn(II ) to Mn(IV ) and the interfacial lithium storage upon cycling contribute to the enhanced specific capacity. The excellent rate capability benefits from the presence of conductive graphene and a short transportation length for both lithium ions and electrons. Moreover, the as‐formed hybrid nanostructure of MnO on graphene may help achieve faster kinetics of conversion reactions. |
| |
Keywords: | anodes cycling behavior manganese oxide graphene lithium ion batteries |
|
|