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Liquid Fuels from Alternative Carbon Sources Minimizing Carbon Dioxide Emissions
Authors:Matthew J Metzger  Benjamin J Glasser  Bilal Patel  James Fox  Baraka Celestin Sempuga  Diane Hildebrandt  David Glasser
Affiliation:1. Dept. of Chemical and Biochemical Engineering, Rutgers University, , Piscataway, NJ, 08854;2. Dept. of Chemical and Metallurgical Engineering, Centre of Material and Process Synthesis, University of the Witwatersrand, , Johannesburg, South Africa
Abstract:The energy needs of the world continue to grow, as does the resulting environmental impact. Policy makers continue to call for alternative energies to replace today's petroleum‐based liquid fuels. However, liquid fuels have significant advantages, and it is probably unwise to abandon the existing infrastructure without appropriately exploring alternatives to lessen the environmental burden of producing liquid fuels. Biomass and coal are often proposed as alternatives to petroleum‐based carbon sources, but those processes lose a significant amount of their potential product to unwanted carbon dioxide emissions. However, combining biomass and coal with cleaner natural gas yields processes with less environmental impact to produce liquid fuels with small, zero, or even negative carbon dioxide emissions. Our process synthesis approach is applied to commonly encountered liquid fuel production methods to identify promising routes and to establish feasibility limits on those less promising alternatives. © 2013 American Institute of Chemical Engineers AIChE J, 59: 2062–2078, 2013
Keywords:process synthesis  flow sheet design  carbon dioxide emission reduction  Fischer‐Tropsch synthesis  systems analysis
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