| 多环芳烃与N—溴代丁二酰亚胺的光化学反应 |
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| 引用本文： | 张卫红 宗志敏. 多环芳烃与N—溴代丁二酰亚胺的光化学反应[J]. 江苏石油化工学院学报, 2000, 12(1): 15-18 |
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| 作者姓名： | 张卫红 宗志敏 |
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| 作者单位： | 江苏石油化工学院化学工程系!江苏常州213016(张卫红)，中国矿业大学能源利用与化学工程系!江苏徐州221008(宗志敏，魏贤勇) |
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| 摘 要： | 在可见光照射 ,苯为溶剂 ,氮气气氛中考察了数种多环芳烃与N -溴代丁二酰亚胺的反应。采用气相色谱跟踪了反应过程 ,解释了产物因结构而异的原因。结果表明 :甲基芳烃仅得到单溴代产物 ,氢化芳烃主要生成脱氢产物 ,蒽全部转化为 9,1 0 -二溴代蒽。
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| 关 键 词： | 溴代丁二酰亚胺 多环芳烃 光溴化反应 气相色谱 |
Photochemical Reaction of Aromatic Hydrocarbon with N-Bromosuccinimide |
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| ZHANG Wei-hong,ZONG Zhi-min,WEI Xian-yong. Photochemical Reaction of Aromatic Hydrocarbon with N-Bromosuccinimide[J]. Journal of Jiangsu Institute of Petrochemical Technology, 2000, 12(1): 15-18 |
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| Authors: | ZHANG Wei-hong ZONG Zhi-min WEI Xian-yong |
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| Affiliation: | ZHANG Wei-hong1,ZONG Zhi-min2,WEI Xian-yong2 |
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| Abstract: | Using benzene as solvent ,the reactions of several aromatic hydrocarbons with N-bromosuccinimide at visible light and nitrogen atmosphere were examined. The reaction processes were traced by GC and the causes of different resultants were explored. The results show that methyl aromatic hydrocarbons merely produced mono-bromide and that hydrogenated aromatic hydrocarbons predominantly afforded dehydrogenated products ,whereas all of anthracene turned into 9,10-dibromoanthracene. |
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| Keywords: | N-bromosuccimide aromatic hydrocarbon photochemical reaction |
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