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Structure and magnetic properties of Fe1−xCox nanowires in self-assembled arrays
Authors:G.H. Yue   X. Wang   L.S. Wang   P. Chang   R.T. Wen   Y.Z. Chen  D.L. Peng  
Affiliation:aDepartment of Materials Science & Engineering, Research Center of Materials Design & Applications, Xiamen University, Xiamen 361005, People's Republic of China;bSchool of Physical Science & Technology, Lanzhou University, Lanzhou 730000, People's Republic of China
Abstract:Fe1−xCox nanowires in self-assembled arrays with varying compositions were produced by the template-assisted pulsed electrochemical deposition method. The structural and magnetic properties of the arrays were investigated using several experimental techniques. TEM analyses indicated that the nanowires were regular, uniform, 8 μm in length and 50 nm in diameter. The results of X-ray diffraction indicated that the body-centered-cubic (bcc) (α), face-centered-cubic (fcc) (γ), and hexagonal-close-packed (hcp) (var epsilon) Fe–Co phases appeared in different compositions. Magnetic measurements showed that the coercivity and squareness of the hysteresis loops of the Fe1−xCox changed with their compositions, which may be attributable to shape anisotropy. The room temperature 57Fe Mössbauer spectra of the arrays of the Fe1−xCox nanowires revealed strong shape anisotropy.
Keywords:Fe1−  xCox nanowires   Magnetic properties   Electrochemical deposition
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