Affiliation: | 1. Centre for Advanced Macromolecular Design and Australian Centre for NanoMedicine, School of Chemical Engineering, The University of New South Wales, Sydney, NSW, 2052 Australia;2. Centre for Advanced Macromolecular Design and Australian Centre for NanoMedicine, School of Chemical Engineering, The University of New South Wales, Sydney, NSW, 2052 Australia Department of Chemistry, Faculty of Engineering and Natural Science, Bursa Technical University, Bursa, 16310 Turkey;3. Materials Research Laboratory and Departments of Materials, Chemistry and Biochemistry, University of California, Santa Barbara, CA, 93106 USA |
Abstract: | Recent achievements and future opportunities for the design of 2D, 3D, and 4D materials using photochemical reactions are summarized. Light is an attractive stimulus for material design due to its outstanding spatiotemporal control, and its ability to mediate rapid polymerization under moderate reaction temperatures. These features have been significantly enhanced by major advances in light generation/manipulation with light-emitting diodes and optical fiber technologies which now allows for a broad range of cost-effective fabrication protocols. This combination is driving the preparation of sophisticated 2D, 3D, and 4D materials at the nano-, micro-, and macrosize scales. Looking ahead, future challenges and opportunities that will significantly impact the field and help shape the future of light as a versatile and tunable design tool are highlighted. |