Effect of substituent groups for formation of organic-metal hybrid nanowires by charge-transfer of tetrathiafulvalene derivatives with metal ion |
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| Authors: | K Naka D Ando Y Chujo |
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| Affiliation: | 1. Department of Chemistry and Materials Technology, Graduate School of Science and Technology, Kyoto Institute of Technology, Matsugasaki, Sakyo-ku, Kyoto 615-8585, Japan;2. Department of Polymer Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8585, Japan |
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| Abstract: | Effect of substituent groups on a tetrathiafulvalene (TTF) unit for formation of organic-metal hybrid nanowires was studied. Depend on the substituent groups, the nanowires were obtained as a precipitate just by mixing TTF derivatives and HAuCl4 in CH3CN solution at room temperature via electron transfer reaction between the TTF derivatives and a gold ion. To precede favorably hybrid nanowire formation, increase planarity and introduction of strong interaction on the TTF derivatives are required. |
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