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铋含量对钛酸镧铋陶瓷结构和介电性能的影响
引用本文:方频阳,樊慧庆,LIU Lai-jun,QIU Shao-jun,CHEN Jin.铋含量对钛酸镧铋陶瓷结构和介电性能的影响[J].材料科学与工程学报,2007,25(6):895-898.
作者姓名:方频阳  樊慧庆  LIU Lai-jun  QIU Shao-jun  CHEN Jin
作者单位:1. 西北工业大学材料学院,凝固技术国家重点实验室,陕西,西安,710072
2. State Key Laboratory of Solidification Processing, School of Materials Science and Engineering, Northwestern Polytechnical University, Xi'an 710072, China
基金项目:Foundation item: National Nature Science Foundation (50672075) and the Xi'an S&T Research Foundation (GG05015, GG06023 ), the SRFDP (20050699011 ) and EYTP and NCET Program of M0E, Science Creative Foundation (2006CR06) NPU of China.
摘    要:通过固相合成的方法制备了Bi3.25,LaxTi3O12(x=0.98~1.03,简称BLT)陶瓷。通过XRD,SEM和阻抗分析仪表征了陶瓷的晶体结构和晶体形貌,测试了陶瓷的介电频谱,结果表明陶瓷的晶体结构为典型的层状钙钛矿结构且不随Bi含量和温度的变化而改变;随着Bi含量的增加晶体形貌由棒状颗粒向片状颗粒转变,而且陶瓷的致密度也得到提高;介电常数随Bi含量的增加先增大后减小,并且在x=1.02时达到最大值。

关 键 词:铋层状钙钛矿结构  BLT  介电性能  铁电陶瓷  Bi-layer  perovskite  structure  BLT  dielectric  properties  ferroelectric  ceramics  铋含量  钛酸镧铋  陶瓷结构  介电性能  影响  Technique  Conventional  Ceramics  Bismuth  Titanate  Dielectric  Properties  Structure  Content  maximum  dielectric  constant  decreases  scanning  electron  microscopy  morphology  crystal  structure  increasing  bismuth  titanate
文章编号:1673-2812(2007)06-0895-04
收稿时间:2006-06-01
修稿时间:2007-07-11

Influence of Bi Content on the Structure and Dielectric Properties of Lanthanum-modified Bismuth Titanate Ceramics by the Conventional Solid-solution Technique
FANG Pin-yang,FAN Hui-qing,LIU Lai-jun,QIU Shao-jun,CHEN Jin.Influence of Bi Content on the Structure and Dielectric Properties of Lanthanum-modified Bismuth Titanate Ceramics by the Conventional Solid-solution Technique[J].Journal of Materials Science and Engineering,2007,25(6):895-898.
Authors:FANG Pin-yang  FAN Hui-qing  LIU Lai-jun  QIU Shao-jun  CHEN Jin
Abstract:Lanthanum-modified bismuth titanate, Bi3.25-x La0.75Ti3O12 (BLT) ceramics, with x ranging from 0.98 to 1.03 were prepared by the conventional solid-solution technique. The crystal structure, morphological and dielectric properties of BLT ceramics were investigated by the X-ray diffraction (XRD), the scanning electron microscopy (SEM) and the impendence analyzer. It is indicated that the crystal structure of ceramic is a classic Bi-layer perovskite structure. The crystal structure doesn't change with bismuth content and the sintering temperature. The micro morphology transformes from stick-like crystal grains to slice-like crystal grains with bismuth content increasing . The dielectric constant firrstly increases then decreases with increasing content of bismuth, and arrives at a maximum at x = 1.02.
Keywords:Bi-layer perovskite structure  BLT  dielectric properties  ferroelectric ceramics
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