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五氧化二氮对一元取代苯的硝化研究
引用本文:蔡春,吕春绪.五氧化二氮对一元取代苯的硝化研究[J].火炸药学报,2000,23(1):25-27.
作者姓名:蔡春  吕春绪
作者单位:南京理工大学化工学院,江苏,南京,210094
摘    要:研究了五氧化二氮在惰性溶剂中对甲苯,氯苯及硝基苯进行的硝化反应。在甲苯的一段硝化产物中p-MNT的生成比例可提高5%以上,在氯苯的硝化产物中,o-MNCB生成比例有明显提高,在硝基苯的硝化产物中,间二硝基苯的比例可高达97%以上。,

关 键 词:硝化  五氧化二氮  硝化剂  异构体  氧化氮
文章编号:1007-7812(2000)01-0025-03
修稿时间:1999-03-29

Investigation on Nitration of Monosubstituted Benzene with Nitrogen Pentoxide
CAI Chun,L Chun-xu.Investigation on Nitration of Monosubstituted Benzene with Nitrogen Pentoxide[J].Chinese Journal of Explosives & Propellants,2000,23(1):25-27.
Authors:CAI Chun  L Chun-xu
Affiliation:CAI Chun,L(U) Chun-xu
Abstract:Nitration of toluene, chlorobenzene, nitrobenzene in inactive organic solvents have been investigated. In mononitration of toluene, the ratio of p MNT have an increase more than 5%, in nitration product of chcorobenzene, the ratio of o MNCB could be increased obviously, and the retio of m DNB could be reached as high as 97% in nitration product of nitrobenzene.
Keywords:Nitraiton  Nitrogen pentoxide  Isomer
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