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Model-based Analysis of Fixed-bed and Membrane Reactors of Various Scale
Authors:Jan P Walter  Andreas Brune  Andreas Seidel-Morgenstern  Christof Hamel
Affiliation:1. Otto von Guericke University Magdeburg, Institute of Process Engineering, Universitätsplatz 2, 39106 Magdeburg, Germany;2. Otto von Guericke University Magdeburg, Institute of Process Engineering, Universitätsplatz 2, 39106 Magdeburg, Germany

Anhalt University of Applied Sciences, Process Engineering, Bernburger Straße 55, 06354 Köthen, Germany;3. Otto von Guericke University Magdeburg, Institute of Process Engineering, Universitätsplatz 2, 39106 Magdeburg, Germany

Max Planck Institute for Dynamics of Complex Technical Systems, Sandtorstraße 1, 39106 Magdeburg, Germany

Abstract:A packed-bed membrane reactor in a distributor configuration is studied theoretically for the oxidative propane dehydrogenation and compared with a fixed-bed reactor. Based on detailed 2D models considering two different heat and mass transport models the reactor scale-up including various reactor-to-particle diameter ratios (D/dP) is analyzed with respect to reactor performance, heat transfer and hot spot formation. Higher selectivities at lower hot spot temperatures occur in the packed-bed membrane reactor for the same reaction conditions.
Keywords:2D Modelling  Heterogeneous catalysis  Membrane reactors  Propane dehydrogenation  Scale-up
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