Solvothermal Synthesis of Ternary Sulfides of Sb2 ? x
Bi
x
S3 (x = 0.4, 1) with 3D Flower-Like Architectures |
| |
Authors: | Jiquan Sun Xiaoping Shen Lijun Guo Guoxiu Wang Jinsoo Park Kun Wang |
| |
Affiliation: | 1. School of Chemistry and Chemical Engineering, Jiangsu University, 212003, Zhenjiang, China 2. School of Mechanical, Materials and Mechatronics Engineering, University of Wollongong, Wollongong, NSW, 2522, Australia
|
| |
Abstract: | Flower-like nanostructures of Sb2 ? xBixS3(x = 0.4, 1.0) were successfully prepared using both antimony diethyldithiocarbamate Sb(DDTC)3] and bismuth diethyldithiocarbamate Bi(DDTC)3] as precursors under solvothermal conditions at 180 °C. The prepared Sb2 ? xBixS3 with flower-like 3D architectures were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray spectrometry (EDS), high-resolution transmission electron microscopy (HRTEM), and selected area electron diffraction (SAED). The flower-like architectures, with an average diameter of ~4 μm, were composed of single-crystalline nanorods with orthorhombic structures. The optical absorption properties of the Sb2 ? xBixS3 nanostructures were investigated by UV–Visible spectroscopy, and the results indicate that the Sb2 ? xBixS3 compounds are semiconducting with direct band gaps of 1.32 and 1.30 eV for x = 0.4 and 1.0, respectively. On the basis of the experimental results, a possible growth mechanism for the flower-like Sb2 ? xBixS3 nanostructures is suggested. |
| |
Keywords: | Nanostructures Semiconductor Ternary sulfide Solvothermal Optical properties |
本文献已被 SpringerLink 等数据库收录! |
|