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纳米CuO/CoFe2O4-TiO2模拟太阳光降解亚甲基蓝的性能
引用本文:陈浩,蒋金芝,阎建辉,张丽. 纳米CuO/CoFe2O4-TiO2模拟太阳光降解亚甲基蓝的性能[J]. 工业催化, 2011, 19(5): 64-69. DOI: 10.3969/j.issn.1008-1143.2011.05.014
作者姓名:陈浩  蒋金芝  阎建辉  张丽
作者单位:1.中南大学化学化工学院,湖南 长沙 410083;2.湖南理工学院化学化工系,湖南 岳阳 414000
摘    要:采用溶胶-凝胶法制备CuO/CoFe2O4粒子,并与P25复合制备纳米催化剂CuO/CoFe2O4-TiO2.通过模拟太阳光催化降解亚甲基蓝,对催化剂活性进行研究,采用SEM、TEM、XRD和UV-Vis DRS方法对催化剂进行表征.结果表明,CuO/CoFe2O4粒子均匀分散在P25微粒表面,平均粒径为60 nm.并...

关 键 词:催化化学  纳米催化剂CuO/CoFe2O4-TiO2  光催化降解  亚甲基蓝

Research on the properties of nano-catalyst CuO/CoFe2O4-TiO2 for photocatalytic degradation of methylene blue under visible light
CHEN Hao,JIANG Jinzhi,YAN Jianhui,ZHANG Li. Research on the properties of nano-catalyst CuO/CoFe2O4-TiO2 for photocatalytic degradation of methylene blue under visible light[J]. Industrial Catalysis, 2011, 19(5): 64-69. DOI: 10.3969/j.issn.1008-1143.2011.05.014
Authors:CHEN Hao  JIANG Jinzhi  YAN Jianhui  ZHANG Li
Affiliation:1.School of Chemistry and Chemical Engineering, Central South University, Changsha 410083, Hunan, China;;2.Department of Chemistry and Chemical Engineering, Hunan Institute of Science and Technology, Yueyang 414000, Hunan, China
Abstract:CuO/CoFe2O4 particles were prepared by sol gel method and CuO/CoFe2O4 TiO2 composite catalysts were synthesized by CuO/CoFe2O4 and Degussa P25.Photocatalytic activity of as prepared nanocomposites was investigated using the degradation of methylene blue aqueous solution under visible light irradiation as the probe reaction.The catalysts were characterized by XRD,SEM,TEM and UV-Vis DRS.The results showed that CuO/CoFe2O4 nanoparticles deposited on the surface of Degussa P25 nanopariticles were dispersed well and the average size was about 60 nm.The influence of catalyst types,P25 contents in CCFP(CuO/CoFe2O4 doped with P25),light intensity,calcination temperature and methylene blue adsorption rate was studied.The results indicated that the catalyst CCFP-70 doped with 70wt% P25 for degradation of methylene blue exhibited better activity than that of pure TiO2 and P25.The degradation rate of methylene blue reached 99% under 250 W xenon lamp for 60 minutes.
Keywords:catalytic chemistry nano catalyst CuO/CoFe2O4TiO2 photocatalysis degradation methylene blue
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