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Phase transitions and fluctuations in classical statistical mechanics |
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| Authors: | G.?A.?Martynov author-information" > author-information__contact u-icon-before" > mailto:g@migmail.ru" title=" g@migmail.ru" itemprop=" email" data-track=" click" data-track-action=" Email author" data-track-label=" " >Email author |
| Affiliation: | 1.Institute of Physical Chemistry and Electrochemistry,Russian Academy of Sciences,Moscow,Russia |
| Abstract: | It is shown that allowance for fluctuations leads to the appearance of additional terms in the Hamiltonian of the system and in the thermodynamic parameters of the substance. As a result, it becomes possible to describe the critical phenomena and phase transitions of liquid–vapor within classical statistical mechanics (without taking into account fluctuations, this is impossible). |
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