Dual-layer membrane with hierarchical hydrophobicity and transport channels for nonpolar organic solvent nanofiltration |
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Authors: | Zheng-Jun Fu Zhen-Yuan Wang Mei-Ling Liu Jing Cai Pu-An Yuan Qian Wang Weihong Xing Shi-Peng Sun |
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Affiliation: | State Key Laboratory of Materials-Oriented Chemical Engineering, Jiangsu National Synergetic Innovation Center for Advanced Materials, College of Chemical Engineering, Nanjing Tech University, Nanjing, China |
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Abstract: | Nonpolar solvent separation is widely used in petroleum, chemical, food industries, but traditional separation methods consume intensive energy. State-of-art organic solvent nanofiltration membranes require complex modifications for nonpolar solvent transport. For the first time, we propose the concurrent modification of the surface, interface and support layer of dual-layer membranes with three additives (perfluorodecylamine, fluoro substituted aromatic amine, silica nanoparticles) in a one-step cocasting process. A delamination-free dual-layer membrane was obtained with a hierarchical hydrophobicity and transport channels. The novel designed structure elevated the pure n-hexane permeance (28.75 L m−2 hr−1 bar−1) by 3 orders of magnitude with a high lecithin rejection (98.7%). This method of synergistically controlling the hierarchical structures and properties of dual-layer membranes can significantly shorten the preparation process of high-performance nonpolar solvent nanofiltration membranes. |
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Keywords: | cocasting dual-layer membranes hydrophobicity nonpolar solvent organic solvent nanofiltration |
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