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克劳斯尾气加氢催化剂的器外硫化技术研究
引用本文:苗超,陈昌介,夏勇,温崇荣,何金龙,刘建.克劳斯尾气加氢催化剂的器外硫化技术研究[J].石油与天然气化工,2016,45(3):16-20.
作者姓名:苗超  陈昌介  夏勇  温崇荣  何金龙  刘建
作者单位:中国石油西南油气田公司天然气研究院,中国石油西南油气田公司天然气研究院,中国石油长庆油田分公司第一采气厂,中国石油西南油气田公司天然气研究院,中国石油西南油气田公司天然气研究院,中国石油西南油气田公司川西北气矿天然气净化厂
摘    要:研发了反应温度不同的两种固体硫化剂,并将该类硫化剂应用于克劳斯尾气加氢催化剂的硫化反应。对硫化剂的添加量、硫化过程中的操作条件进行了考察,通过能谱分析法确定活性组分的硫化率可达到硫化要求,通过催化剂性能评价确定催化剂可达到性能指标的要求,明确了提前硫化技术在克劳斯尾气加氢催化领域的可行性。

关 键 词:硫化  加氢催化剂  克劳斯  尾气  
收稿时间:2015/9/25 0:00:00

Research of ex-situ sulfurization technology on Claus tail gas hydrogenation catalyst
Miao Chao,Chen Changjie,Xia Yong,Wen Chongrong,He Jinlong and Liu Jian.Research of ex-situ sulfurization technology on Claus tail gas hydrogenation catalyst[J].Chemical Engineering of Oil and Gas,2016,45(3):16-20.
Authors:Miao Chao  Chen Changjie  Xia Yong  Wen Chongrong  He Jinlong and Liu Jian
Affiliation:Research Institute of Natural Gas Technology, PetroChina Southwest Oil & Gasfield Company, Chengdu 610213, China,Research Institute of Natural Gas Technology, PetroChina Southwest Oil & Gasfield Company, Chengdu 610213, China,The first Natural Gas Plant, PetroChina Changqing Oilfield Company, Jingbian 718500, China,Research Institute of Natural Gas Technology, PetroChina Southwest Oil & Gasfield Company, Chengdu 610213, China,Research Institute of Natural Gas Technology, PetroChina Southwest Oil & Gasfield Company, Chengdu 610213, China and Natural Gas Purification Plant, Northwestern Sichuan Gas District PetroChina Southwest Oil & Gasfield Company, Jiangyou 621700, China
Abstract:Two solid sulfurizing agents used under different reaction temperatures were developed as ex-situ sulfurization catalysts of Claus tail gas hydrogenation. By studying the sulfurizing agents addition and the operating condition during the sulfurization process, it was determined that the sulfurization rate of the catalyst active components could reach the standard with the method of Energy Dispersive Spectrometer. The results of catalyst performance evaluation showed that catalyst could meet the performance requirement, which definited the feasibilities of sulfurization technology in Claus tail gas hydrogenation catalytic field.
Keywords:sulfurization  hydrogenation catalyst  Claus  tail gas
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