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Porous Nanocomposites 2: Pore-Structure Stability of Pure ZrO2, ZrO2(matrix)-Al2O3 and Al2O3(matrix)-ZrO2 Nanocomposites
Authors:Padmakumar Nair  Jalajakumari Nair  EBM Doesburg  JG van Ommen  JRH Ross  AJ Burggraaf  Y Oosawa  F Mizukami
Affiliation:(1) Faculty of Chemical Technology, University of Twente, P.O. Box 217, 7500 AE Enschede, The Netherlands;(2) National Institute of Materials and Chemical Research, 1-1 Higashi, Tsukuba, Ibaraki, 305, Japan
Abstract:Porous nanocomposites in the Al2O3-ZrO2 system were studied with a view to understand the selection rules for developing high temperature stable porous oxide systems. The results were also compared with TiO2-Al2O3 nanocomposite systems. The pore structure and phase evolution of these composites were studied using TG/DTA, XRD and nitrogen adsorption/desorption techniques. Al2O3 was found to be a good second phase stabiliser for stabilising ZrO2 and TiO2 matrix phases.
Keywords:nanocomposites  nanostructured oxides  pore-structure stability  surface area
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