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巯基乙酸2—乙基己酯的合成
引用本文:菅秀君,张剑,姜新,甄丽丽. 巯基乙酸2—乙基己酯的合成[J]. 精细与专用化学品, 2001, 9(1): 18-19
作者姓名:菅秀君  张剑  姜新  甄丽丽
作者单位:齐鲁石化公司研究院
摘    要:本文介绍了巯基乙酸2-乙基己酯产品的用途、性能以及合成路线。以2-乙基己醇和氯乙酸为起始反应原料,采用先酯化后巯基化的合成工艺,催化剂活性高、反应步骤少、产品收率高,解决了先巯基化后酯化工艺过程复杂、对巯基乙酸纯度要求高、生产成本高的难题,是具有较高工业化实践价值的新生产工艺。

关 键 词:氯乙酸  2-乙基己醇  巯基乙酸2-乙基己酯

Synthesis of 2-Ethyl Hexyl Mercaptoacetate
Jian Xiujun,Zhang Jian,Jiang Xin,Zhen Lili. Synthesis of 2-Ethyl Hexyl Mercaptoacetate[J]. Fine and Specialty Chemicals, 2001, 9(1): 18-19
Authors:Jian Xiujun  Zhang Jian  Jiang Xin  Zhen Lili
Affiliation:Jian Xiujun Zhang Jian Jiang Xin Zhen Lili
Abstract:The application, performance and synthesis route of 2-ethyl hexyl mercaptoacetate product are introduced in this article. The synthesis process which adopts esterification firstly, then sulfhydrylation is based on starting materials 2-ethyl hexanol and chloroacetic acid. The activity of the catalyst is high, reaction steps are few and overall yield of product is high. Difficulties including complex process of sulfhydrylation first and then esterification, requirement of high purity of mercaptoacetic acid, and high production cost have been overcome. This new manufacturing process has a high commercial value.
Keywords:chloroacetic acid   2-ethyl hexanol   2-ethyl hexyl mercaptoacetate  
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