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ZnO-B_2O_3掺杂陶瓷的微观结构和微波介电性能
引用本文:刘立新,张玉华,陆茵,刘欣宁.ZnO-B_2O_3掺杂陶瓷的微观结构和微波介电性能[J].粉末冶金工业,2017,27(5).
作者姓名:刘立新  张玉华  陆茵  刘欣宁
作者单位:河南工业职业技术学院机械工程学院,河南南阳,473009
摘    要:研究了ZnO-B_2O_3(ZB_2)对(Ca_(0.254)Li_(0.19)Sm_(0.14))TiO_3陶瓷的烧结行为和微波介电性能的影响。结果表明:ZnO-B_2O_3添加质量分数为3%时,试样的相对密度达到最大值;烧结温度从1 300℃降低到1 100℃时,试样的微波介电性能没有衰减。添加3%ZB_2(质量分数)的(Ca_(0.254)Li_(0.19)Sm_(0.14))TiO_3陶瓷在1 100℃烧结3 h呈现出较好的微波介电性能,介电常数ε_r=108.2,品质因数Q_f=6 545 GHz,共振频率温度系数τf=6.5×10~(-6)/℃,表明ZB_2是一种有效改善(Ca_(0.254)Li_(0.19)Sm_(0.14))TiO_3陶瓷致密性和微波介电性能的烧结助剂。

关 键 词:ZnO-B2O3  微波介电性能  致密化  陶瓷  烧结行为

Microstructure and microwave dielectric properties of ZnO-B2O3 doped ceramics
LIU Li-xin,ZHANG Yu-hua,LU Yin,LIU Xin-ning.Microstructure and microwave dielectric properties of ZnO-B2O3 doped ceramics[J].Powder Metallurgy Industry,2017,27(5).
Authors:LIU Li-xin  ZHANG Yu-hua  LU Yin  LIU Xin-ning
Abstract:The effects of ZnO-B2O3(ZB2) on the sintering behavior and microwave dielectric properties of (Ca0.254Li0.19Sm0.14)TiO3 ceramics were investigated. Results show that the relative densities of the specimens reach the maximum value when adding 3%ZB2(mass percent). The sintering temperature is lowered from 1300℃to 1100℃without degradation of the microwave dielectric properties. The(Ca0.254Li0.19Sm0.14 )TiO3 ceramic with 3%ZB2(mass percent)sintered at 1100 ℃ for 3 h shows good microwave dielectric properties,which is εr=108.2,Qf=6545 GHz,andτf=6.5×10-6/℃,indicating that ZB2 is an effective sintering aid to improve the den-sification and microwave dielectric properties of(Ca0.254Li0.19Sm0.14)TiO3 ceramics.
Keywords:ZnO-B2O3  microwave dielectric property  densification  ceramic  sintering behavior
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