Theoretical models and experimental results on the temperature dependence of polyfluorene solar cells |
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| Authors: | Fengling Zhang, Sasa Lacic, Mattias Svensson, Mats R. Andersson,Olle Ingan s |
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| Affiliation: | aDepartment of Physics and Measurement Technology, Linköping University, SE-58183 Linköping, Sweden;bMaterials and Surface Chemistry/Polymer Technology, Chalmers University of Technology, SE-412 96 Göteborg, Sweden;cCenter of Organic Electronics, Linköping University, Linkoping, Sweden |
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| Abstract: | The temperature dependence of device parameters of polymer solar cells based on alternating copolyfluorene incorporating dioctyl-fluorene and di-thienyl-benzothiadiazole (APFO-3) mixed with [6,6]-phenyl-C61-butyric acid methylester (PCBM) was modeled theoretically by simulation and investigated experimentally under illumination of AM1.5 (100 mW/cm2). Both simulation and experimental results show photocurrent, fill factor and power conversion efficiency all increase, and the open-circuit voltages monotonically decrease with temperature increase from room temperature (RT) to 120 °C. These results can be explained by taking into account the temperature dependence of the mobility, and the thermal activation of the injection current from the electrodes. The increase of PCE with temperature is a distinguishing feature of polymer solar cells. |
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| Keywords: | Polymers solar cells Temperature dependence Modeling |
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