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Polyether-segmented nylon hemodialysis membranes. IV. Membrane morphologies and permeability characteristics of dialysis membrane composed of poly(ethylene oxide)-segmented Ny69/M10
Authors:Akira Mochizuki  Yukio Seita  Nobuko Saiga  Shuzo Yamashita
Abstract:
Dialysis membrane was prepared by a phase inversion method using a new polyether-segmented nylon which dissolves in common organic solvents such as dimethylsulfoxide. The polyether-segmented nylon contained poly(ethylene oxide) block and nylon block (random copolyamide: Ny69/M10) prepared by sebacic acid, azelaic acid, m-xylenediamine, and hexamethylenediamine. The morphologies and permeability characteristics of the membranes were investigated. It was shown by scanning electron microscope observation that the membrane had a fingerlike structure when dimethylsulfoxide was used as a polymer solvent, and a spongelike structure when an additive such as calcium chloride was added to the polymer solution. The high permeability for the solutes such as urea and vitamin B12 were observed in comparison with the polyether-segmented Ny610 membranes prepared by a phase inversion method. © 1997 John Wiley & Sons, Inc. J Appl Polym Sci 65:1731–1737, 1997
Keywords:dialysis membrane  phase inversion method  solute permeability  membrane morphology  polyether-segmented nylon
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