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Interface Stability of the SiC Particles/Fe Matrix Composite System
作者姓名:TANG  Wenming  ZHENG  Zhixiang  WU  Yucheng  JIN  Zhihao
作者单位:[1]School of Materials Science and Engineering, Hefei University of Technology, Hefei 230009, China [2]School of Materials Science and Engineering, Xi'an Jiaotong University, Xi'an 710009, China
摘    要:The interface reaction between the SiC particles ( SiCp ) and Fe was stndicd during sintering the SiCp reinforced Fe matrix composites at 1423 K for 1 h. In the composite having 3wt% (weight ratio) SiCp (the 3SiCp/ Fe composite), the interface reaction products of Fe3 Si, the carbon precipitates, and Fe3 C or pearlite were generated. Fe3 Si coustructs the bright matrix of the reaction zone in the original situation of the SiCp. The carbon precipitates are randondy embedded in the reaction zone. Fe3 C or pearlite exists at the grain boundaries of the Fe matrix. As increasing the SiCp concentration in the SiCp/ Fe composite, the inteusity of the interface reaction between SiCp and Fe iacreases. After the 10SiCp/ Fe composite ( having 10wt .% SiCp ) sintered at 1423 K for 1 h, all of SiCp are decomposed, and replaced by the reaction zone composed of Fe3 Si and the carbon precipitates. No Fe3 C or pearlite was genertaed during the reaction. The effects of the techniques of oxidizing of SiCp , coating SiCp by interaction with the Cr powder, and alloying the Fe matrix by adding the Cr element on the interface stability of the SiCp/ Fe composite system were also investigated, respectitely. The oxide membrane and the coating layer on SiCp can inhibit the interface reaction between SiCp and Fe by isolating SiCp from the Fe matrix during sintering. The interface reaction does not occur in the 3 SiCp/ Fe- 10 Cr composite but in the 3 SiCp/ Fe-5 Cr composite. In the SiCp/ Fe-Cr alloy composites, the interface reaction between SiCp and the Fe- Cr alloys is weaker than that between SiCp and Fe . The Cr element behaves as a diluent, it causes a redaction in the interface reaction, which is proportional to the amount of the element added.

关 键 词:界面反应  界面稳定性  碳化硅/铁复合系统  合金化
收稿时间:2005-02-24
修稿时间:2005-12-23

Interface stability of the SiC particles/Fe matrix composite system
TANG Wenming ZHENG Zhixiang WU Yucheng JIN Zhihao.Interface Stability of the SiC Particles/Fe Matrix Composite System[J].Journal of Wuhan University of Technology. Materials Science Edition,2006,21(3):49-53.
Authors:Tang Wenming Ph D  Zheng Zhixiang  Wu Yucheng  Jin Zhihao
Affiliation:(1) School of Materials Science and Engineering, Hefel University of Technology, 230009 Hefei, China;(2) School of Materials Science and Engineering, Xi'an Jiaotong University, 710009 Xi'an, China
Abstract:The interface reaction between the SiC particles (SiCp) and Fe was studied during sintering the SiCp reinforced Fe matrix composites at 1423 K for 1 h. In the composite having 3wt% (weight ratio) SiCp (the 3SiCp/Fe composite), the interface reaction products of Fe_3Si, the carbon precipitates, and Fe_3C or pearlite were generated. Fe_3Si constructs the bright matrix of the reaction zone in the original situation of the SiCp. The carbon precipitates are randomly embedded in the reaction zone. Fe_3C or pearlite exists at the grain boundaries of the Fe matrix. As increasing the SiCp concentration in the SiCp/Fe composite, the intensity of the interface reaction between SiCp and Fe increases. After the 10SiCp/Fe composite (having 10wt.% SiCp) sintered at 1423 K for 1 h, all of SiCp are decomposed, and replaced by the reaction zone composed of Fe_3Si and the carbon precipitates. No Fe_3C or pearlite was generated during the reaction. The effects of the techniques of oxidizing of SiCp, coating SiCp by interaction with the Cr powder, and alloying the Fe matrix by adding the Cr element on the interface stability of the SiCp/Fe composite system were also investigated, respectively. The oxide membrane and the coating layer on SiCp can inhibit the interface reaction between SiCp and Fe by isolating SiCp from the Fe matrix during sintering. The interface reaction does not occur in the 3SiCp/Fe-10Cr composite but in the 3SiCp/Fe-5Cr composite. In the SiCp/Fe-Cr alloy composites, the interface reaction between SiCp and the Fe-Cr alloys is weaker than that between SiCp and Fe. The Cr element behaves as a diluent, it causes a reduction in the interface reaction, which is proportional to the amount of the element added.
Keywords:interface reaction  interface stability  oxidation of SiC  coating  alloying
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