Composite silicone rubber of high piezoresistance repeatability filled with nanoparticles |
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Authors: | JuYing Wu ChengXi Zhou QingWen Zhu EnRong Li Ge Dai Long Ba YuHong Huang Jun Mei |
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Affiliation: | (1) Laboratory of Applied Environmental Chemistry, University of Kuopio, Patteristonkatu 1, 50101 Mikkeli, Finland;(2) Department of Chemistry, University of Bath, Bath, BA2 7AY, UK; |
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Abstract: | The ruthenium oxide nanoparticles with size less than 20 nm were fabricated by annealing the metallic ruthenium nanoparticles
in air, which were synthesized by using the thermal reduction in the polyol solution. The rutile structure of the ruthenium
oxide was proved by using transmission electron microscopy (TEM) and X-ray photoelectron spectroscopy (XPS). The oxide has
good electron conductivity. The surface of the ruthenium oxide was modified by a vinyl silane coupling agent. The assembling
of the silane to the oxide surface was proved by Infrared (IR) absorption spectroscopy. By mixing the nanoparticles with poly(methylvinylsiloxane)
(PMVS) silicone rubber, a composite filled with dispersive conducting phase was fabricated. The temperature dependent conductivity
shows that the electron transportation through composite is mainly dominated by tunneling. The measurement of piezoresistance
shows that the composite at low strain has high piezoresistance repeatability. The 3D reconstruction images of the composite
filled with carbon black or ruthenium oxide show that the aggregation of the nanoparticles differs much for two composites.
The narrow distribution range of the particle size was thought to be the main factor for the high piezoresistance recurrence. |
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