The co-carbonization of oxidized coals with pitches and decacyclene |
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Authors: | Zhanfen Qian Harry Marsh |
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Affiliation: | 1. Northern Carbon Research Laboratories, School of Chemistry, University of Newcastle upon Tyne, Newcastle upon Tyne NE1 7RU, UK;1. Anshan Research Institute of Thermo-energy, Anshan, Liaoning, People''s Republic of China |
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Abstract: | Coals of rank (NCB) 701, 401 and 204 were oxidized in air at 371 K for up to 15 days. The changes in optical texture of cokes from these coals were monitored by optical microscopy and point counting. The oxidized coals were cocarbonized to 1273 K with up to 30% of A240 petroleum pitch, a hydrogenated coal extract and decacyclene, and the resultant cokes were reassessed. The increase in isotropy in cokes caused by the oxidation treatment was never completely removed by use of the additives, but significant improvements existed for the less extensively oxidized coals. The possibility exists of using co-carbonization of oxidized coals with additives in coke making. Additives with good hydrogen donor ability, as with the coal extract, appear to be the most suitable. |
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Keywords: | coal oxidation hydrogen transfer |
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