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Fenton氧化深度处理焦化废水的研究
引用本文:赖鹏,赵华章.Fenton氧化深度处理焦化废水的研究[J].当代化工,2012(1):11-14.
作者姓名:赖鹏  赵华章
作者单位:[1]国家开发银行股份有限公司四川省分行,四川成都610027 [2]北京大学环境工程系,北京100871
基金项目:国家自然科学基金资助项目 项目号:20607001
摘    要:采用Fenton氧化对焦化废水进行了深度处理。结果表明:Fenton氧化反应迅速,可迅速降低焦化废水生化出水的COD;H2O2和Fe2+的投加量对Fenton氧化具有明显的影响;pH=3时反应体系具有最佳的COD去除效果。在H2O2投加量为1.994 mL/L,FeSO4.7H2O投加量为0.543 g/L,pH=3,温度为35℃的条件下,反应出水COD低于100 mg/L,去除率可达72.7%;Fenton氧化可有效去除生化出水中的难降解有机物。实验结果表明Fenton氧化是深度处理焦化废水的有效工艺。

关 键 词:Fenton氧化  焦化废水  深度处理  难降解有机物

Study on Advanced Treatment of Coking Wastewater by Fenton Oxidation Process
LAI Peng,ZHAO Hua-zhang.Study on Advanced Treatment of Coking Wastewater by Fenton Oxidation Process[J].Contemporary Chemical Industry,2012(1):11-14.
Authors:LAI Peng  ZHAO Hua-zhang
Affiliation:1.China Development Bank Sichuan Branch,Sichuan Chengdu 610027,China; 2.Department of Environmental Engineering,Peking University,Beijing 100871,China)
Abstract:Advanced treatment of coking wastewater by Fenton oxidation process was studied.The results show that the COD can be removed quickly by Fenton oxidation,dosages of H2O2 and Fe2+ can obviously affect the COD removal efficiency.The best COD removal efficiency can be gotten when pH=3.When dosages of H2O2 and Fe2+ are 1.994 mL/L and 0.543 g/L respectively,the COD can be removed to less than 100 mg/L at pH=3 and 35 ℃,and the COD removal efficiency is up to 72.7%.Fenton oxidation process can effectively remove refractory organic compounds in coking wastewater.Therefore,Fenton oxidation process is an effective means for advanced treatment of coking wastewater.
Keywords:Fenton oxidation  Coking wastewater  Advanced treatment  Refractory organic compounds
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