| 金鸡纳碱及其衍生物在不对称Mannich反应中的应用 |
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| 引用本文： | 潘昭喜,何永光,刘浩. 金鸡纳碱及其衍生物在不对称Mannich反应中的应用[J]. 广州化工, 2012, 0(3): 20-22 |
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| 作者姓名： | 潘昭喜 何永光 刘浩 |
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| 作者单位： | 贵州大学,贵州贵阳550025 |
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| 摘 要： | 不对称Mannich反应是一种应用最广泛的合成光学活性的手性氨基酸衍生物的方法,近几年基于金鸡纳碱及其衍生物的有机小分子催化的不对称Mannich反应成为国内外研究的热点,本文简要介绍了金鸡纳碱及其衍生物在不对称Mannich反应中的应用。
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| 关 键 词： | Mannich 金鸡纳碱 不对称 |
Application of Cinchona Alkaloid and their Derivatives in Asymmetric Mannich Reactions |
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| PAN Zhao-xi,HE Yong-guang,LIU Hao. Application of Cinchona Alkaloid and their Derivatives in Asymmetric Mannich Reactions[J]. GuangZhou Chemical Industry and Technology, 2012, 0(3): 20-22 |
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| Authors: | PAN Zhao-xi HE Yong-guang LIU Hao |
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| Affiliation: | (Guizhou University,Guizhou Guiyang 550025,China) |
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| Abstract: | Catalytic enantioselective Mannich reactions provided one of the most versatile approaches for the synthesis of optically active chiral amines.Recently,several organocatalytic protocols were developed by using the parent cinchona alkaloids or their derivatives.It was a focus of considerable attention in the domestic and foreign research.The recent progress of asymmetric Mannich reactions catalyzed by cinchona alkaloids or their derivatives was generally reviewed. |
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| Keywords: | Mannich cinchona alkaloid asymmetric |
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