| 钯铂催化剂的除氢活性及其表面性质 |
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| 引用本文： | 过中儒,徐慧珍,徐贤伦.钯铂催化剂的除氢活性及其表面性质[J].石油化工,1992(6). |
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| 作者姓名： | 过中儒 徐慧珍 徐贤伦 |
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| 作者单位： | 浙江工学院化工系，浙江工学院化工系，中科院兰州化学物理研究所 杭州 310014，杭州 310014，兰州 730000 |
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| 摘 要： | 研究了Pd-Al_2O_3,Pt-Al_2O_3,Pd-Pt-Al_2O_3催化剂的除氢活性。试验结果表明,Pd-Pt-Al_2O_3双金属催化剂的除氢活性,抗硫性和抗CO性能较Pd-Al_2O_3,Pt-Al_2O_3单金属催化剂好。稳定性试验和工业试验表明,Pd-Pt-Al_2O_3双金属催化剂具有良好的稳定性和工业应用效果。采用TEM,TPR,IR和ESCA对催化剂表面性质进行研究的结果表明,Pd-Pb-Al_2O_3双金属催化剂的表面性质和Pd-Al_2O_3,Pt-Al_2O_3单金属催化剂的不同。Pd-Pb-Al_2O_3双金属催化剂中两种金属之间可能发生相互作用并形成金属簇的新相。
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Hydrogen-Removal Activity and Surface Properties of Pd-Pt-Al_2O_3 Catalysts |
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| Abstract: | The hydrogen-removal activity(HRA) of Pd-Al_2O_3, Pt-Al_2O_3, and Pd-Pt-Al_2O_3 catalysts was studied. It was found that the HRA and the resistance to S or CO of Pd-Pt-Al_2O_3 bimetallic catalyst were higher than that of Pd-Al_2O_3 and Pt-Al_2O_3 monometallic catalysts. The stability and industrial tests showed that the Pd-Pt-Al_2O_3 bimetallic catalyst had good stability and performance in industrial applications. The surface properties of catalysts wcre characterized by TEM, TPR, IR, and ESCA, It was observed that the surface properties of Pd-Pt-Al_2O_3 bimetallic catalyst were different from that of Pd-Al_2O_3 and Pt-Al_2O_3 monometallic catalysts. It seems that there may be some interaction between the two metals in the bimetallic catalyst with the formation of a new phase of metal cluster. |
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