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Influence of the surface etching on the corrosion behaviour of a three-dimensional printed Ti–6Al–4V alloy
Authors:Jaroslav Fojt  Zdenek Kacenka  Eva Jablonska  Vojtech Hybasek  Eva Pruchova
Affiliation:1. Department of Metals and Corrosion Engineering, University of Chemistry and Technology, Prague, Prague, Czech Republic;2. Department of Biochemistry and Microbiology, University of Chemistry and Technology, Prague, Prague, Czech Republic
Abstract:Recently, there has been an extension of three-dimensional (3D) printing technology of metal materials in the medical field. Additive technology has made it possible to manufacture customized implants. However, 3D printing products often require surface treatment. The possible treatments include acid etching. This study investigated the effect of surface etching on the corrosion resistance of Ti–6Al–4V alloy concerning biological applications. The samples were etched in a mixture of hydrofluoric acid and nitric acid. The corrosion behaviour was described by measuring the time dependence of polarization resistance in a saline solution and surface analysis. The results showed that etching creates a fluoride-rich layer on the surface, which negatively affects the corrosion behaviour of the material for up to 24 hr. Cytocompatibility tests showed that the resulting layer does not affect the biocompatibility of the material.
Keywords:additive manufacturing  corrosion  cytotoxicity  surface etching  titanium alloy
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