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Natural graphite reinforced fluoroelastomer composites: Morphological,mechanical, thermal,dielectric, and solvent transport studies
Authors:Grace Moni  Anshida Mayeen  Soney C. George
Affiliation:1. Centre for Nanoscience and Technology, Amal Jyothi College of Engineering, Kanjirappally, Kerala, India

School of Chemical Sciences, M G University, Kottayam, Kerala, India;2. School of Pure and Applied Physics, M G University, Kottayam, Kerala, India;3. Centre for Nanoscience and Technology, Amal Jyothi College of Engineering, Kanjirappally, Kerala, India

Abstract:Fluoroelastomer (FKM) composite embedded with natural graphite (NG) was prepared and its thermal, mechanical, dielectric, and solvent transport properties were explored as a function of NG loading. The morphology of the composites was done by AFM, SEM, and TEM analysis, and XRD provides the structural analysis. The composite with 20 phr of NG content showed the highest tensile properties and thermal stability and was supported by fracture surface SEM analysis. Enhancement in polymer-filler interaction in the composite was further confirmed by the increase in Tg value obtained from DSC analysis. The dielectric permittivity value showed tremendous increment by 30 phr of NG addition with decreased dielectric loss. The resistance to solvent uptake with increase in NG loading by the formation of tortuous pathway is also a clear evidence for the exfoliation of the graphite flakes in the FKM matrix. Better inclusion of NG in FKM matrix efficiently enhanced the thermal, mechanical, dielectric and the transport properties of the composites.
Keywords:fluoroelastomer  mechanical and dielectric properties  morphology  natural graphite  solvent transport
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