| 离子液体在金属离子萃取分离中的应用 |
| |
| 引用本文： | 沈兴海,徐超,刘新起,褚泰伟. 离子液体在金属离子萃取分离中的应用[J]. 核化学与放射化学, 2006, 28(3): 129-138 |
| |
| 作者姓名： | 沈兴海 徐超 刘新起 褚泰伟 |
| |
| 作者单位： | 北京大学,化学与分子工程学院,应用化学系,北京分子科学国家实验室,北京,100871;北京大学,化学与分子工程学院,应用化学系,北京分子科学国家实验室,北京,100871;北京大学,化学与分子工程学院,应用化学系,北京分子科学国家实验室,北京,100871;北京大学,化学与分子工程学院,应用化学系,北京分子科学国家实验室,北京,100871 |
| |
| 摘 要： | 离子液体作为绿色溶剂是溶剂萃取分离金属离子方面研究的热点.介绍了以离子液体为溶剂时,萃取分离各种金属离子的效果,包括碱金属、碱土金属、过渡金属、稀土及锕系金属,以及核燃料后处理涉及的铀、钚及裂变产物等多种离子,深入探讨了其萃取机理.展望了离子液体取代有毒、易挥发、易造成环境污染的有机溶剂的发展和应用前景.
|
| 关 键 词： | 离子液体 萃取 分离 金属离子 |
| 文章编号： | 0253-9950(2006)03-0129-10 |
| 收稿时间： | 2006-06-01 |
| 修稿时间： | 2006-06-01 |
Ionic Liquids Used in Extraction and Separation of Metal Ions |
| |
| SHEN Xing-hai,XU Chao,LIU Xin-qi,CHU Tai-wei. Ionic Liquids Used in Extraction and Separation of Metal Ions[J]. Journal of Nuclear and Radiochemistry, 2006, 28(3): 129-138 |
| |
| Authors: | SHEN Xing-hai XU Chao LIU Xin-qi CHU Tai-wei |
| |
| Abstract: | Ionic liquids as green solvents now have become a research hotspot in the field of separation of metal ions by solvent extraction. Experimental results of extraction of various metal ions with ionic liquids as solvents, including that of alkali metals, alkaline earths, transition metals rare earths and actinides are introduced. The extraction of uranium, plutonium and fission products that are involved in spent nuclear fuel reprocessing is also reviewed. The possible extraction mechanisms are discussed. Finally, the prospect of replacement of volatile and/or toxic organic solvents with environmentally benign ionic liquids for solvent extraction and the potency of applications of ionic liquids in solvent extraction are also commented. |
| |
| Keywords: | ionic liquids extraction separation metal ions |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
| 点击此处可从《核化学与放射化学》浏览原始摘要信息 |
|
点击此处可从《核化学与放射化学》下载全文 |
|
