Solvent-induced assembly of two supramolecular isomers of Mn thiophenedicarboxylate coordination polymers |
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| Authors: | Hong-Bo Yuan Shi-Yao Yang Zhao-Xiong Xie Rong-Bing Huang Stuart R Batten |
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| Affiliation: | aState Key Laboratory of Physical Chemistry of Solid Surface and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China;bSchool of Chemistry, Monash University, Victoria 3800, Australia |
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| Abstract: | Two supramolecular isomers of MnII thiophenedicarboxylate coordination polymers, namely, Mn2(tdc)2(dmf)2]n (1) and Mn3(tdc)3(dmf)3]n (2) (H2tdc = 2,5-thiophenedicarboxylic acid, dmf = N,N-dimethylformamide), were synthesized with solvent-induced assembly method and the antiferromagnetic interactions between the MnII ions in their solid phase were measured. |
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| Keywords: | Supramolecular isomerism Coordination polymers Crystal structure Solvent-induced Anti-ferromagnetic |
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