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力场下聚合物的结晶行为研究进展
引用本文:闵敏,芦艾.力场下聚合物的结晶行为研究进展[J].塑料科技,2007,35(7):98-103.
作者姓名:闵敏  芦艾
作者单位:1. 西南科技大学材料科学与工程学院,四川,绵阳,621002
2. 西南科技大学材料科学与工程学院,四川,绵阳,621002;中国工程物理研究院化工材料研究所,四川,绵阳,621900
摘    要:介绍了聚合物在力场作用下结晶行为的研究进展;概述了不同力场(剪切、拉伸、振动)对聚合物结晶形态和结晶动力学的影响;重点论述了剪切力场下,剪切速率、剪切方式、分子量和分子量分布等对聚合物成核和生长的影响,简述了拉伸、振动对结晶的影响。认为力场的加入对聚合物的成核和晶体生长都有促进作用。

关 键 词:聚合物  力场  结晶形态  结晶动力学
文章编号:1005-3360(2007)07-0098-06
修稿时间:2007-04-05

Research Advancement of Polymer Crystallization Behavior under Stress Field
Min Min,Lu Ai.Research Advancement of Polymer Crystallization Behavior under Stress Field[J].Plastics Science and Technology,2007,35(7):98-103.
Authors:Min Min  Lu Ai
Affiliation:1.Department of material, Southwest University of Science and Technology, Mianyang 621002 China; 2.Institute of Chemical Materials of CAEP, Mianyang 621900 China
Abstract:This article mainly reviewed the advancement of polymer crystallization behavior under stress field,it summarized the influence of the various kinds of stress (shearing,tensiling, vibrating) on the crystal morphology of polymer and crystallization kinetics.It discussed that how the nucleation of polymer and crystal growth individually depend on the shear rate,shear form,molecular weight and its distribution,and that the existence of stress field benefits the nucleation and crystal growth.It also summarized the effects of tension and vibration on polymer crystallization.
Keywords:Polymer  Stress field  Crystal morphology  Crystallization kinetics
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